A switchable hydrogenation chemoselectivity of biomass platform compounds based on solvent regulation

被引：17

作者：

Zhang, Yuanjing ^{[1
]}

Wang, Si ^{[1
]}

Yang, Yusen ^{[1
,2
]}

Wang, Lei ^{[1
,2
]}

Xu, Enze ^{[1
]}

Hou, Quandong ^{[1
]}

Zhao, Shiquan ^{[1
]}

Liu, Tianyong ^{[1
]}

Hong, Song ^{[1
]}

Zheng, Lirong ^{[3
]}

Li, Feng ^{[1
]}

Zhang, Xin ^{[1
,2
]}

Wei, Min ^{[1
,2
]}

机构：

[1] Beijing Univ Chem Technol, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China

[2] Quzhou Inst Innovat Resource Chem Engn, Quzhou 324000, Peoples R China

[3] Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China

来源：

APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY | 2024年 / 346卷

基金：

中国国家自然科学基金;

关键词：

Solvent effect; Selective hydrogenation; Fully exposed cluster catalyst; Adsorption configuration; Structure -selectivity relationship; ZEOLITE CRYSTALS; SELECTIVITY; CONVERSION; REDUCTION;

D O I：

10.1016/j.apcatb.2024.123719

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Selective catalytic conversion of biomass-derived compounds to fuels and fine chemicals serves as a renewable energy pathway for the partial substitution of fossil resources, in which reaction pathway and selectivity control are key issues. Herein, we report a fully exposed Pt clusters immobilized on CoAl mixed metal oxides catalyst (denoted as Ptn/CoAl-MMOs), which exhibits prominent catalytic performance towards liquid phase hydrogenation reaction of furfural (FAL). Noteworthily, the hydrogenation chemoselectivity can be switched among four products via using four different solvents: tetrahydrofurfuryl alcohol (THFA; yield: 91.4%), furfuryl alcohol (FA; yield: 97.7%), 2-methylfuran (2-MF; yield: 92.1%) and furan (FU; yield: 90.8%) are obtained in ethanol, dioxane, isopropanol and n-hexane solvent, respectively. Experimental studies (in situ FT-IR and TPSR-Mass) combined with theoretical calculations (DFT) reveal that solvent molecules exert an essential influence on the adsorption configuration of FAL via changing the solvent-catalyst and/or substrate-catalyst interaction, which ultimately determines the hydrogenation pathway, key intermediate and final product. This work demonstrates a facile solvent-dependent product-switching strategy within one catalytic system, which opens up potential opportunities for tailoring hydrogenation selectivity in liquid-solid catalytic reactions towards biomass upgrading.

引用

页数：10

共 37 条

[1] Solvent molecules form surface redox mediators in situ and cocatalyze O2 reduction on Pd [J].

Adams, Jason S. ;

Chemburkar, Ashwin ;

Priyadarshini, Pranjali ;

Ricciardulli, Tomas ;

Lu, Yubing ;

Maliekkal, Vineet ;

Sampath, Abinaya ;

Winikoff, Stuart ;

Karim, Ayman M. ;

Neurock, Matthew ;

Flaherty, David W. .

SCIENCE, 2021, 371 (6529) :626-+

[2] Critical role of solvent-modulated hydrogen-binding strength in the catalytic hydrogenation of benzaldehyde on palladium [J].

Cheng, Guanhua ;

Jentys, Andreas ;

Gutierrez, Oliver Y. ;

Liu, Yue ;

Chin, Ya-Huei ;

Lercher, Johannes A. .

NATURE CATALYSIS, 2021, 4 (11) :976-985

[3]

Deng P., 2023, Angew. Chem. Int. Ed.

[4] Solvent Tunes the Selectivity of Hydrogenation Reaction over α-MoC Catalyst [J].

Deng, Yuchen ;

Gao, Rui ;

Lin, Lili ;

Liu, Tong ;

Wen, Xiao-Dong ;

Wang, Shuai ;

Ma, Ding .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (43) :14481-14489

[5] Efficient Decarbonylation of Furfural to Furan Catalyzed by Zirconia-Supported Palladium Clusters with Low Atomicity [J].

Ishida, Tamao ;

Kume, Kurumi ;

Kinjo, Kota ;

Honma, Tetsuo ;

Nakada, Kengo ;

Ohashi, Hironori ;

Yokoyama, Takushi ;

Hamasaki, Akiyuki ;

Murayama, Haruno ;

Izawa, Yusuke ;

Utsunomiya, Masaru ;

Tokunaga, Makoto .

CHEMSUSCHEM, 2016, 9 (24) :3441-3447

[6] Furfural - a versatile, biomass-derived platform chemical for the production of renewable chemicals [J].

Jaswal, Anurag ;

Singh, Piyush Pratap ;

Mondal, Tarak .

GREEN CHEMISTRY, 2022, 24 (02) :510-551

[7] Fully Exposed Platinum Clusters on a Nanodiamond/Graphene Hybrid for Efficient Low-Temperature CO Oxidation [J].

Jia, Zhimin ;

Peng, Mi ;

Cai, Xiangbin ;

Chen, Yunlei ;

Chen, Xiaowen ;

Huang, Fei ;

Zhao, Linmin ;

Diao, Jiangyong ;

Wang, Ning ;

Xiao, Dequan ;

Wen, Xiaodong ;

Jiang, Zheng ;

Liu, Hongyang ;

Ma, Ding .

ACS CATALYSIS, 2022, :9602-9610

[8] Metal-acid interfaces enveloped in zeolite crystals for cascade biomass hydrodeoxygenation [J].

Jin, Zhu ;

Yi, Xianfeng ;

Wang, Liang ;

Xu, Shaodan ;

Wang, Chengtao ;

Wu, Qinming ;

Wang, Lingxiang ;

Zheng, Anmin ;

Xiao, Feng-Shou .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2019, 254 :560-568

[9] Local Structure and Electronic State of Atomically Dispersed Pt Supported on Nanosized CeO2 [J].

Kottwitz, Matthew ;

Li, Yuanyuan ;

Palomino, Robert M. ;

Liu, Zongyuan ;

Wang, Guangjin ;

Wu, Qin ;

Huang, Jiahao ;

Timoshenko, Janis ;

Senanayake, Sanjaya D. ;

Balasubramanian, Mahalingam ;

Lu, Deyu ;

Nuzzo, Ralph G. ;

Frenkel, Anatoly I. .

ACS CATALYSIS, 2019, 9 (09) :8738-8748

[10] Selective hydrogenation of 5-(hydroxymethyl)furfural to 5-methylfurfural over single atomic metals anchored on Nb2O5 [J].

Li, Shaopeng ;

Dong, Minghua ;

Yang, Junjuan ;

Cheng, Xiaomeng ;

Shen, Xiaojun ;

Liu, Shulin ;

Wang, Zhi-Qiang ;

Gong, Xue-Qing ;

Liu, Huizhen ;

Han, Buxing .

NATURE COMMUNICATIONS, 2021, 12 (01)

← 1 2 3 4 →