Dynamic Interfacial Tensions of Surfactant and Polymer Solutions Related to High-Temperature and High-Salinity Reservoir

被引:6
作者
Cui, Xiang-Long [1 ]
Pan, Yi [1 ]
Hu, Fu-Tang [2 ]
Han, Lu [3 ]
Zhu, Xiu-Yu [2 ]
Zhang, Lei [4 ]
Zhou, Zhao-Hui [3 ]
Li, Gen [5 ]
Ma, Gui-Yang [1 ]
Zhang, Lu [4 ]
机构
[1] Liaoning Petrochem Univ, Coll Petr Engn, Fushun 113001, Peoples R China
[2] PetroChina Qinghai Oilfield Co, Res Inst Drilling & Prod Technol, Dunhuang 736202, Peoples R China
[3] PetroChina Res Inst Petr Explorat & Dev, State Key Lab Enhanced Oil Recovery, Beijing 100083, Peoples R China
[4] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China
[5] Northeast Petr Univ, Dept Petr Engn, Daqing 163318, Peoples R China
关键词
betaine; polymer; interfacial tension; n-alkanes; crude oil; CRUDE-OIL; GEMINI SURFACTANT; ADSORPTION-KINETICS; WATER; MECHANISM; ASPHALTENES; STABILITY; BEHAVIOR; SYSTEMS; BETAINE;
D O I
10.3390/molecules28031279
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Betaine is a new surfactant with good application prospects in high-temperature and high-salinity reservoirs. The interfacial properties of two kinds of betaine mixtures with a good synergistic effect were evaluated in this paper. On this basis, the effects of temperature-resistant, salt-resistant polymers with different contents of 2-acrylamide-2-methylpropanesulfonic acid (AMPS) on dynamic interfacial tensions (IFTs) against n-alkanes and crude oil were studied. The experimental results show that the IFTs between betaine ASB and n-alkanes can be reduced to ultra-low values by compounding with anionic surfactant petroleum sulfonate (PS) and extended anionic surfactant alkoxyethylene carboxylate (AEC), respectively. ASB@AEC is very oil-soluble with n(min) value >= 14, and ASB@PS is relatively water-soluble with n(min) value of 10. The water solubility of both ASB@PS and ASB@AEC is enhanced by the addition of water-soluble polymers. The HLB of the ASB@AEC solution becomes better against crude oil after the addition of polymers, and the IFT decreases to an ultra-low value as a result. On the contrary, the antagonistic effect in reducing the IFT can be observed for ASB@PS in the same case. In a word, polymers affect the IFTs of surfactant solutions by regulating the HLB.
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页数:12
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