Crystal structure and Hirshfeld surface analysis of 4-cyano-N-[(4-cyanophenyl)sulfonyl]-N-[2-(5-methylfuran-2-yl)phenyl]benzenesulfonamide

被引：1
|
作者：
Mammadova, Gunay Z. [1 ]
Yakovleva, Elizaveta D. [2 ]
Burkin, Gleb M. [2 ]
Khrustalev, Victor N. [2 ,3 ]
Akkurt, Mehmet [4 ]
Celiksesir, Sevim Turktekin [4 ]
Bhattarai, Ajaya [5 ]
机构：
[1] Baku State Univ, Organ Chem Dept, Z Xalilov Str 23, AZ-1148 Baku, Azerbaijan
[2] Peoples Friendship Univ Russia, RUDN Univ, 6 Miklukho Maklaya St, Moscow 117198, Russia
[3] RAS, Zelinsky Inst Organ Chem, 4,7 Leninsky Prospect, Moscow 119991, Russia
[4] Erciyes Univ, Dept Phys, Fac Sci, TR-38039 Kayseri, Turkiye
[5] M M A M C Tribhuvan Univ, Dept Chem, Biratnagar, Nepal
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷
关键词：
crystal structure; sulfonamides; hydrogen bonds; C-H center dot center dot center dot pi interactions; pi-pi interactions; Hirshfeld surface analysis; ANTIBACTERIAL; ANTIFUNGAL; INHIBITORS;
D O I：
10.1107/S2056989023006254
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, C25H17N3O5S2, intramolecular pi-pi interactions [centroid-to-centroid distance = 3.5640 (9) angstrom] are observed between the furan and benzene rings of the 4-cyanophenyl group. In the crystal, molecules are connected via C-H center dot center dot center dot O and C-H center dot center dot center dot N hydrogen bonds, forming layers parallel to the (100) plane. These layers are interconnected by C-H center dot center dot center dot pi interactions and weak van der Waals interactions. Hirshfeld surface analysis indicates that H center dot center dot center dot H (30.2%), N center dot center dot center dot H/H center dot center dot center dot N (22.3%), C center dot center dot center dot H/H center dot center dot center dot C (17.9%) and O center dot center dot center dot H/H center dot center dot center dot O (15.4%) interactions make the most significant contributions to the crystal packing.
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收藏
页码：747 / +
页数：11
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