MOF-derived porous NiCo2O4 nanofile arrays as an efficient anode material for rechargeable Li-ion batteries

被引:21
作者
Babu, S. Kishore [1 ]
Jayachandran, M. [2 ]
Vivek, P. [1 ]
Das, Himadri Tanaya [3 ]
Vijayakumar, T. [2 ]
Gunasekaran, B. [1 ]
机构
[1] SRM Inst Sci & Technol, Coll Engn & Technol, Dept Phys & Nanotechnol, Srm Nagar 603203, Tamil Nadu, India
[2] SRM Inst Sci & Technol, Coll Engn & Technol, Futurist Mat Res Ctr Planetary Explorat, Dept Phys & Nanotechnol, Srm Nagar 603203, Tamil Nadu, India
[3] Utkal Univ, Ctr Adv Mat & Applicat, Bhubneswar 751004, Odisha, India
关键词
Metal-Organic Framework; Li-ion battery; Nanofile arrays; ELECTROCHEMICAL PERFORMANCE; CARBON COMPOSITE; LITHIUM;
D O I
10.1016/j.jallcom.2023.171555
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Due to their vast surface area and superior porosity structure, metal-organic frameworks (MOFs) derived materials have recently presented a significant promise for better lithium-ion batteries (LIBs). Herein, we synthesised MOF-derived porous NiCo2O4 nanofile arrays from a simple solvothermal technique followed by calcination at 450 degrees C. The prepared sample was characterized by X-ray diffraction, thermogravimetric, highresolution transmission electron microscopy, X-ray photoelectron spectroscopy and Brunauer-Emmett-Teller. The acquired nanofile array morphology achieved a large specific surface area of 189 m2/g can shorten the Li ions (Li+) transport and enhance the electrochemical performance. As expected, the prepared electrode reveals a discharge-specific capacity of around 1120 mAh/g at a 0.1 C rate. At 2 C rate, the electrode's specific capacity can still reach 210 mAh/g after 100 cycles. The pseudocapacitive nature of NiCo2O4 was determined by kinetic analysis, revealing the diffusion-controlled faradaic behaviour. Our prepared electrode material is considered an attractive option for the anode material in rechargeable Li-ion batteries because it has been proven to have a relatively good specific capacity and cycling stability.
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页数:8
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