Synthesis of Isothiocyanates from Primary Amines via Visible-Light Photocatalysis

被引:9
作者
Ma, Jinglin [1 ]
Li, Fengxi [1 ]
Wang, Chunyu [2 ]
Wang, Zhi [1 ]
Du, Chuang [3 ]
Wang, Lei [1 ]
机构
[1] Jilin Univ, Sch Life Sci, Key Lab Mol Enzymol & Engn, Minist Educ, Changchun 130023, Peoples R China
[2] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130023, Peoples R China
[3] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Jilin, Peoples R China
关键词
CHEMISTRY; THIOUREAS; APOPTOSIS; CELLS;
D O I
10.1021/acs.orglett.3c02193
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A photocatalyzed, efficient, and mild approach for thesynthesisof various substituted isothiocyanates from amine and carbon disulfidewas reported in this work. This approach expands the scope of photocatalyticapplications and provides a new method for the preparation of aliphaticand aromatic isothiocyanates, which are significant organic buildingblocks and biological diagnostic markers.
引用
收藏
页码:5692 / 5696
页数:5
相关论文
共 38 条
  • [21] 2-Z
  • [22] ISOTHIOCYANATES IN THE CHEMISTRY OF HETEROCYCLES
    MUKERJEE, AK
    ASHARE, R
    [J]. CHEMICAL REVIEWS, 1991, 91 (01) : 1 - 24
  • [23] Visible light photoredox catalysis: applications in organic synthesis
    Narayanam, Jagan M. R.
    Stephenson, Corey R. J.
    [J]. CHEMICAL SOCIETY REVIEWS, 2011, 40 (01) : 102 - 113
  • [24] Radical-Cascade Avenue to Access 1,2-Dithioles Employing Dithioesters and Edman's Reagent
    Pali, Pragya
    Singh, Maya Shankar
    [J]. ORGANIC LETTERS, 2023, 25 (13) : 2258 - 2263
  • [25] Dehydrogenative coupling reactions catalysed by Rose Bengal using visible light irradiation
    Pan, Yuanhang
    Kee, Choon Wee
    Chen, Li
    Tan, Choon-Hong
    [J]. GREEN CHEMISTRY, 2011, 13 (10) : 2682 - 2685
  • [26] Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
    Prier, Christopher K.
    Rankic, Danica A.
    MacMillan, David W. C.
    [J]. CHEMICAL REVIEWS, 2013, 113 (07) : 5322 - 5363
  • [27] Photocatalysis. A multi-faceted concept for green chemistry
    Ravelli, Davide
    Dondi, Daniele
    Fagnoni, Maurizio
    Albini, Angelo
    [J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (07) : 1999 - 2011
  • [28] 4-Dimethylaminopyridine-catalyzed synthesis of isothiocyanates from amines and carbon disulfide
    Rong, Hao-Jie
    Chen, Tao
    Xu, Ze-Gang
    Su, Tian-Duo
    Shang, Yu
    Wang, Yong-Qiang
    Yang, Cui-Feng
    [J]. TETRAHEDRON LETTERS, 2021, 68
  • [29] Synthesis of Isothiocyanates and Unsymmetrical Thioureas with the Bench-Stable Solid Reagent (Me4N)SCF3
    Scattolin, Thomas
    Klein, Alexander
    Schoenebeck, Franziska
    [J]. ORGANIC LETTERS, 2017, 19 (07) : 1831 - 1833
  • [30] STAAB HA, 1962, LIEBIGS ANN CHEM, V657, P104