Synthesis of Isothiocyanates from Primary Amines via Visible-Light Photocatalysis

被引:9
作者
Ma, Jinglin [1 ]
Li, Fengxi [1 ]
Wang, Chunyu [2 ]
Wang, Zhi [1 ]
Du, Chuang [3 ]
Wang, Lei [1 ]
机构
[1] Jilin Univ, Sch Life Sci, Key Lab Mol Enzymol & Engn, Minist Educ, Changchun 130023, Peoples R China
[2] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130023, Peoples R China
[3] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Jilin, Peoples R China
关键词
CHEMISTRY; THIOUREAS; APOPTOSIS; CELLS;
D O I
10.1021/acs.orglett.3c02193
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A photocatalyzed, efficient, and mild approach for thesynthesisof various substituted isothiocyanates from amine and carbon disulfidewas reported in this work. This approach expands the scope of photocatalyticapplications and provides a new method for the preparation of aliphaticand aromatic isothiocyanates, which are significant organic buildingblocks and biological diagnostic markers.
引用
收藏
页码:5692 / 5696
页数:5
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