Ag-Cu Embedded SDS Nanoparticles for Efficient Removal of Toxic Organic Dyes from Water Medium

被引:29
作者
Ali, Faisal [1 ]
Mehmood, Saira [1 ]
Ashraf, Adnan [1 ]
Saleem, Aimon [1 ]
Younas, Umer [1 ]
Ahmad, Awais [1 ,10 ]
Bhatti, Muhammad Pervaiz [11 ]
Eldesoky, Gaber E. [2 ]
Aljuwayid, Ahmed Muteb [2 ]
Habila, Mohamed A. [2 ]
Bokhari, Awais [3 ]
Mubashir, Muhammad [4 ]
Chuah, Lai Fatt [5 ]
Chong, Jun Wei Roy [6 ]
Show, Pau Loke [6 ,7 ,8 ,9 ]
机构
[1] Univ Lahore, Dept Chem, Lahore 54590, Pakistan
[2] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia
[3] COMSATS Univ Islamabad, Dept Chem Engn, Islamabad 54000, Punjab, Pakistan
[4] Asia Pacific Univ Technol & Innovat, Sch Engn, Dept Petr Engn, Kuala Lumpur 57000, Malaysia
[5] Univ Malaysia Terengganu, Fac Maritime Studies, Kuala Nerus 21030, Terengganu, Malaysia
[6] Univ Nottingham Malaysia, Fac Sci & Engn, Dept Chem & Environm Engn, Semenyih 43500, Selangor Darul, Malaysia
[7] Wenzhou Univ, Zhejiang Prov Key Lab Subtrop Water Environm & Mar, Wenzhou 325035, Peoples R China
[8] SIMATS Saveetha Sch Engn, Dept Sustainable Engn, Chennai 602105, India
[9] Khalifa Univ, Dept Chem Engn, POB 127788, Abu Dhabi, U Arab Emirates
[10] Univ Cordoba, Dept Quim Organ, E-14014 Cordoba, Spain
[11] Govt Coll Univ, Dept Chem, Lahore 54000, Punjab, Pakistan
关键词
SILVER NANOPARTICLES; INFRARED-SPECTRA; GREEN SYNTHESIS; DEGRADATION; PERFORMANCE; FABRICATION; GINSENG; CARBON;
D O I
10.1021/acs.iecr.2c03460
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Remediation of industrial water pollution is a trending subject to date for the researchers around the globe, due to its detrimental effects on human life as well as aquatic life. Azo dyes are the largest industrial water polluters in respect of volume while anthraquinone the second largest. Therefore, humongous considerations are being enum-erated for the removal and decolorization of azo (AZ) dyestuff; however, for anthraquinone (AQ) dyes, these efforts are considerably minimal; although the later one poses a greater threat to environmental contamination, because of their reinforced structure. The current study is an effort toward this foremost issue. Chemical reduction synthesis of silver-copper (Ag-Cu) bimetallic nanoparticles (BNPs) was achieved using NaBH4 as a reducing agent and sodium dodecyl sulfate (SDS) as a stabilizer. Characterization and morphological evaluation indicates two distinctive UV/vis absorption peaks for Ag and Cu. XRD studies for nanocomposite showed crystallite size of 8.96014 nm having an FCC structure. SEM with EDX confirmed the particle sizes of BNPs and SDS to be 17.14 and 114.56 nm, respectively. Potential catalytic activity and kinetic parameters of Ag-Cu BNPs@SDS were monitored against Methylene Blue (MB), Methyl Orange (MO), and eosin-y (EY). The percentage degradation recorded for the nanocatalyst against MO, MB, and EY was 95.21%, 98.57%, and 96.65%, respectively. This method can be adopted for the removal of multiple dyes from industrial effluent on a larger scale.
引用
收藏
页码:4765 / 4777
页数:13
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