Novel fluorescent probe based on dicoumarin for detection of hydrogen sulfide in real samples

被引：7

作者：

Hong, Tong ^{[1
]}

Cheng, Song ^{[1
]}

Zhong, Xuefang ^{[1
]}

Zuo, Yiwei ^{[1
]}

Dong, Yiming ^{[1
]}

Shi, Zhichuan ^{[1
,2
]}

Zhao, Zhigang ^{[1
,2
,3
]}

机构：

[1] Southwest Minzu Univ, Sch Chem & Environm, Chengdu, Peoples R China

[2] Southwest Minzu Univ, Key Lab Gen Chem Natl Ethn Affairs Commiss, Chengdu, Peoples R China

[3] Southwest Minzu Univ, Sch Chem & Environm, Chengdu 610041, Peoples R China

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2023年 / 70卷 / 02期

关键词：

2,4-dinitrobenzenesulfonyl; dicoumarin; fluorescent probe; hydrogen sulfide; LIVING CELLS; SIGNALING MOLECULES; H2S; DESIGN; DYE;

D O I：

10.1002/jccs.202200417

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel dicoumarin-derived hydrogen sulfide (H2S) selective fluorescent "turn-on " probe 3-(2,4-dinitrobenzenesulfonate)-dicoumarin (DC-HS) created by covalent bonding between the 2,4-dinitrobenzenesulfonyl (DNBS) and the 3-hydroxy-dicoumarin (DC-OH) units. Upon the addition of H2S, the probe DC-HS solution's fluorescence significantly increased, and its appearance is changed from practically colorless to brilliant yellow. Probe DC-HS also showed significant fluorescence amplification that was quantitatively detectable in the concentration range of 0-1.5 mu M and had a low detection limit or limit of detection of 0.2 nM. Moreover, with a high recovery rate and excellent accuracy, the developed fluorescent molecule was used successfully for the analysis of H2S in red wine samples.

引用

页码：136 / 144

页数：9

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