Novel fluorescent probe based on dicoumarin for detection of hydrogen sulfide in real samples

被引:7
作者
Hong, Tong [1 ]
Cheng, Song [1 ]
Zhong, Xuefang [1 ]
Zuo, Yiwei [1 ]
Dong, Yiming [1 ]
Shi, Zhichuan [1 ,2 ]
Zhao, Zhigang [1 ,2 ,3 ]
机构
[1] Southwest Minzu Univ, Sch Chem & Environm, Chengdu, Peoples R China
[2] Southwest Minzu Univ, Key Lab Gen Chem Natl Ethn Affairs Commiss, Chengdu, Peoples R China
[3] Southwest Minzu Univ, Sch Chem & Environm, Chengdu 610041, Peoples R China
关键词
2,4-dinitrobenzenesulfonyl; dicoumarin; fluorescent probe; hydrogen sulfide; LIVING CELLS; SIGNALING MOLECULES; H2S; DESIGN; DYE;
D O I
10.1002/jccs.202200417
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel dicoumarin-derived hydrogen sulfide (H2S) selective fluorescent "turn-on " probe 3-(2,4-dinitrobenzenesulfonate)-dicoumarin (DC-HS) created by covalent bonding between the 2,4-dinitrobenzenesulfonyl (DNBS) and the 3-hydroxy-dicoumarin (DC-OH) units. Upon the addition of H2S, the probe DC-HS solution's fluorescence significantly increased, and its appearance is changed from practically colorless to brilliant yellow. Probe DC-HS also showed significant fluorescence amplification that was quantitatively detectable in the concentration range of 0-1.5 mu M and had a low detection limit or limit of detection of 0.2 nM. Moreover, with a high recovery rate and excellent accuracy, the developed fluorescent molecule was used successfully for the analysis of H2S in red wine samples.
引用
收藏
页码:136 / 144
页数:9
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