Photo-Induced Carbonylation of Aryl Bromides for the Synthesis of Aryl Esters and Amides Under Transition Metal-Free Conditions

被引：1

作者：

Zheng, Yan ^{[1
]}

Teng, Bing-Hong ^{[1
,3
]}

Zhang, Youcan ^{[1
]}

Wu, Xiao-Feng ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China

[2] Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany

[3] Liaoning Normal Univ, Sch Chem & Chem Engn, 850 Huanghe Rd, Dalian 116029, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2023年 / 18卷 / 21期

关键词：

Photo-induced; Aryl bromides; Metal-free; Carbonylation; Esters synthesis; PALLADIUM-CATALYZED CARBONYLATION; HETEROGENEOUS CATALYST; PHOTOREDOX CATALYSIS; CARBOXYLIC-ACIDS; HALIDES; AMINOCARBONYLATION; NANOPARTICLES; AMINES;

D O I：

10.1002/asia.202300766

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this work, we developed a photo-induced carbonylation of aryl bromides under transition metal-free conditions. The reaction shows good activity with alcohol and amine nucleophiles. Various esters and amides were formed from aryl halides and alcohols and amines under mild conditions in moderate to good yields. A photo-induced metal-free carbonylation reaction of aryl bromides has been developed. The method shows good reactivity with alcohol and amine nucleophiles, and a variety of useful aryl esters and amides were synthesized at room temperature in moderate to good yields.image

引用

页数：4

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