Enhancing Electrochemical Performance with g-C3N4/CeO2 Binary Electrode Material

被引:17
作者
Sekhar, M. Chandra [1 ]
Kumar, Nadavala Siva [2 ]
Asif, Mohammad [2 ]
Vattikuti, Surya Veerendra Prabhakar [3 ]
Shim, Jaesool [3 ]
机构
[1] Madanapalle Inst Technol & Sci, Dept Phys, Madanapalle 517325, India
[2] King Saud Univ, Dept Chem Engn, POB 800, Riyadh 11421, Saudi Arabia
[3] Yeungnam Univ, Sch Mech Engn, Gyongsan 38541, South Korea
关键词
supercapacitor; storage device; quantum dots; nanostructure; electrode materials; FABRICATION; NANOSHEETS; COMPOSITE;
D O I
10.3390/molecules28062489
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
An innovative form of 2D/0D g-C3N4/CeO2 nanostructure was synthesized using a simple precursor decomposition process. The 2D g-C3N4 directs the growth of 0D CeO2 quantum dots, while also promoting good dispersion of CeO(2)QDs. This 2D/0D nanostructure shows a capacitance of 202.5 F/g and notable rate capability and stability, outperforming the g-C3N4 electrode, reflecting the state-of-the-art g-C3N4 binary electrodes. The binary combination of materials also enables an asymmetric device (g-C3N4/CeO(2)QDs//AC) to deliver the highest energy density (9.25 Wh/kg) and power density (900 W/kg). The superior rate capacity and stability endorsed the quantum structural merits of CeO(2)QDs and layered g-C3N4, which offer more accessible sites for ion transport. These results suggest that the g-C3N4/CeO(2)QDs nanostructure is a promising electrode material for energy storage devices.
引用
收藏
页数:15
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共 51 条
[1]   Effects of Precursors and Carbon Nanotubes on Electrochemical Properties of Electrospun Nickel Oxide Nanofibers-Based Supercapacitors [J].
Aihemaitituoheti, Reziwanguli ;
Alhebshi, Nuha A. ;
Abudula, Tuerdimaimaiti .
MOLECULES, 2021, 26 (18)
[2]   Nickel-Cobalt Layered Double Hydroxide Nanowires on Three Dimensional Graphene Nickel Foam for High Performance Asymmetric Supercapacitors [J].
Bai, Xue ;
Liu, Qi ;
Zhang, Hongsen ;
Liu, Jingyuan ;
Li, Zhanshuang ;
Jing, Xiaoyan ;
Yuan, Yi ;
Liu, Lianhe ;
Wang, Jun .
ELECTROCHIMICA ACTA, 2016, 215 :492-499
[3]  
Bard A. J., 2001, Electrochemical Methods: Fundamentals and Applications, V2nd
[4]   MOF derived CeO2/CoFe2O4 wrapped by pure and oxidized g-C3N4 sheet as efficient supercapacitor electrode and oxygen reduction reaction electrocatalyst materials [J].
Chameh, Behnam ;
Khosroshahi, Negin ;
Bakhtian, Mahnaz ;
Moradi, Morteza ;
Safarifard, Vahid .
CERAMICS INTERNATIONAL, 2022, 48 (15) :22254-22265
[5]   MnO2/g-C3N4 nanocomposite with highly enhanced supercapacitor performance [J].
Chang, Xueting ;
Zhai, Xinxin ;
Sun, Shibin ;
Gu, Danxia ;
Dong, Lihua ;
Yin, Yansheng ;
Zhu, Yanqiu .
NANOTECHNOLOGY, 2017, 28 (13)
[6]   PEDOT/g-C3N4 binary electrode material for supercapacitors [J].
Chen, Xue ;
Zhu, Xiaoshu ;
Xiao, Yinghong ;
Yang, Xiaodi .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2015, 743 :99-104
[7]   Recent trend of CeO2-based nanocomposites electrode in supercapacitor: A review on energy storage applications [J].
Das, Himadri Tanaya ;
Balaji, Elango ;
Dutta, Swapnamoy ;
Das, Nigamananda ;
Das, Payaswini ;
Mondal, Aniruddha ;
Imran, Muhammad .
JOURNAL OF ENERGY STORAGE, 2022, 50
[8]   Mesostructured g-C3N4 nanosheets interconnected with V2O5 nanobelts as electrode for coin-cell-type-asymmetric supercapacitor device [J].
Devarayapalli, K. C. ;
Lee, K. ;
Do, H-B ;
Dang, N. N. ;
Yoo, K. ;
Shim, J. ;
Vattikuti, S. V. Prabhakar .
MATERIALS TODAY ENERGY, 2021, 21
[9]   Flower-like nanoarchitecture assembled from Bi2S3 nanorod/MoS2 nanosheet heterostructures for high-performance supercapacitor electrodes [J].
Fang, Linxia ;
Qiu, Yan ;
Zhai, Tianli ;
Wang, Fan ;
Lan, Mengdi ;
Huang, Kejing ;
Jing, Qiangshan .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2017, 535 :41-48
[10]   Electrode Materials for Supercapacitors: A Review of Recent Advances [J].
Forouzandeh, Parnia ;
Kumaravel, Vignesh ;
Pillai, Suresh C. .
CATALYSTS, 2020, 10 (09) :1-73