Utilization of metal industry solid waste as an adsorbent for adsorption of anionic and cationic dyes from aqueous solution through the batch and continuous study

Industrial waste, for instance, textile effluents when released into the ecological system without first being treated or with inappropriate levels of treatment, can lead to serious issues deteriorating the environment and human health. Moreover, solid waste from various industries has also become a major issue due to massive urbanization. For instance, the waste from the metal industry has been rapidly increasing such as Jarosite which has various metals, metal oxides, and silica in its composition. Therefore, Jarosite was utilized as an adsorbent for the adsorption of anionic Congo red (CR) and cationic Methylene blue (MB) dyes from aqueous solutions. The processed adsorbent sample was characterized by BET, XRD, SEM, EDS, FTIR, and XPS techniques. The effects of initial dye concentration, pH, adsorbent dose, temperature, and contact time were examined. The metal industry waste is used as a low-cost abundant adsorbent with great potential for adsorption ability to remove the CR (97.5%) and MB (68.5%) at pH 7, contact time 90 min, adsorbent dose 0.1 g, and initial dye concentration 50 mg/L. The adsorption data followed the adsorption isotherm and Kinetics for both dyes. The removal of both dyes was a physical adsorption process, endothermic and spontaneous reaction. Column adsorption investigation was described by AB (Adams-Bohart) and YN (Yoon-Nelson) models. According to the economic view, the utilization of jarosite for dye removal is a cost-effective approach, because it is collected free of cost from industries. Henceforth, for the first time, toxic metal industry waste was successfully utilized as an adsorbent for wastewater treatment.