Processing of Phosphoric Solid Waste by Humic Acid Leaching Method

被引:3
作者
Nazarbek, Ulzhalgas [1 ]
Abdurazova, Perizat [1 ]
Nazarbekova, Saule [1 ]
Raiymbekov, Yerkebulan [1 ]
Kambatyrov, Maksat [1 ]
机构
[1] M Auezov South Kazakhstan Univ, High Sch Chem Engn & Biotechnol, Shymkent 160012, Kazakhstan
关键词
phosphoric sludge; cottrel dust; humic acid; phosphoric acid; amorphous structure; DISSOLUTION KINETICS; PHOSPHATE ORE; RECOVERY; SLUDGE;
D O I
10.3390/inorganics11030090
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This article presents the results of research on the leaching of solid phosphorus-containing waste with humic acid. Such waste includes the by-products of the electrothermal processing of phosphate raw materials-phosphorus sludge and cottrel dust. Chemical and X-ray diffraction analyses have been used to study their composition and phase structure, according to which these substances have an amorphous structure. The leaching of phosphoric sludge and cottrel dust was investigated by varying the main parameters. The obtained data were processed using the method of formal kinetics to study the features of the process. The reaction rate constants and the apparent activation energy were calculated, and the values found made it possible to determine that the process under study is limited by diffusion. The scientific novelty of the article is the use of humic acid for leaching phosphoric solid waste as opposed to traditional methods. This new method may offer improved efficiency, reduced environmental impact, and a potential alternative solution for the processing of phosphoric waste.
引用
收藏
页数:13
相关论文
共 32 条
[1]  
[Anonymous], 1984, 74971984EN ISO ISOTC
[2]   Modelling thermal phosphorus recovery from sewage sludge ash [J].
Arnout, Sander ;
Nagels, Els .
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2016, 55 :26-31
[3]  
Batkaeva N.R., 2010, Patent, Patent No. [No. 23006, 23006]
[4]  
Blankstein V.A., 1974, USSR Patent, Patent No. [No. 421625, 421625]
[5]  
Colbridge D.E.C., 2016, PHOSPHORUS CHEM BIOC, P93
[6]   Fundamentals of the wet-process phosphoric acid production .2. Kinetics and mechanism of CaSO4 center dot 0.5(2)H(2)O surface crystallization and coating formation [J].
Dorozhkin, SV .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1997, 36 (02) :467-473
[7]  
Duisembiev R.N., 2018, SCI WORK M AUEZOV SK, V45, P55
[8]   The activated complex in chemical reactions [J].
Eyring, H .
JOURNAL OF CHEMICAL PHYSICS, 1935, 3 (02) :107-115
[9]   Let's Make White Phosphorus Obsolete [J].
Geeson, Michael B. ;
Cummins, Christopher C. .
ACS CENTRAL SCIENCE, 2020, 6 (06) :848-860
[10]   Second-Generation Phosphorus: Recovery from Wastes towards the Sustainability of Production Chains [J].
Hollas, Camila Ester ;
Bolsan, Alice Chiapetti ;
Venturin, Bruno ;
Bonassa, Gabriela ;
Tapparo, Deisi Cristina ;
Candido, Daniela ;
Antes, Fabiane Goldschmidt ;
Vanotti, Matias B. ;
Szogi, Ariel A. ;
Kunz, Airton .
SUSTAINABILITY, 2021, 13 (11) :NA