Selective oxidation of aqueous organic pollutants over MOFs-based catalysts: A mini review

被引:85
作者
Wang, Fu-Xue [1 ,2 ]
Zhang, Zi-Chen [1 ,2 ]
Wang, Chong-Chen [1 ,2 ]
机构
[1] Beijing Univ Civil Engn & Architecture, Beijing Key Lab Funct Mat Bldg Struct & Environm R, Beijing 100044, Peoples R China
[2] Beijing Univ Civil Engn & Architecture, Beijing Energy Conservat & Sustainable Urban & Rur, Prov & Minist Coconstruct Collaborat Innovat Ctr, Beijing 100044, Peoples R China
基金
中国国家自然科学基金; 北京市自然科学基金;
关键词
MOFs; Composites; derivatives; Selective oxidation; Water decontamination; Chemical oxidation; WASTE-WATER; DEGRADATION; FRAMEWORK; GRAPHENE; MECHANISMS; ADSORPTION; GENERATION; FENTON; OXIDE;
D O I
10.1016/j.cej.2023.141538
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Efficient decontamination from water have attracted global attention in recent years. Advanced oxidation pro-cesses (AOPs) are widely used for aqueous organic pollutants degradation for water purification. However, it still is great challenge to efficiently oxidize the trace micropollutants especially from sewage matrix containing complicated matters, which would consume the reactive species to inhibit the decomposition of the target contaminants. Recently, many researchers devoted to the selective oxidation to address the above-mentioned problem. Various environmental functional materials like metal oxides and carbonaceous materials have been applied as catalysts for selective organic pollutants oxidation. Among them, metal-organic frameworks (MOFs) and their composites/derivatives displayed huge potential due to their designable structure and excellent cat-alytic performance. This review presented the research progress of MOFs-based materials in selective oxidation toward aqueous organic pollutants, in which some examples were analyzed in detail to show their performances, mechanisms as well as influence factors. The unique advantages of MOFs-based materials for selective oxidation were also discussed. Finally, the challenges and prospects of MOFs-based environmental functional materials in selective oxidation from water were proposed.
引用
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页数:10
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