Electrochemical radical-polar crossover: a radical approach to polar chemistry

被引：64

作者：

Tan, Zhoumei ^{[1
]}

Zhang, Haonan ^{[1
]}

Xu, Kun ^{[1
]}

Zeng, Chengchu ^{[1
]}

机构：

[1] Beijing Univ Technol, Fac Environm & Life, Beijing 100124, Peoples R China

来源：

SCIENCE CHINA-CHEMISTRY | 2024年 / 67卷 / 02期

基金：

中国国家自然科学基金; 北京市自然科学基金;

关键词：

electrosynthesis; radical-polar crossover; radical chemistry; polar chemistry; alkene functionalization; ENOL ACETATES; ALKENES; OXYGENATION; ACTIVATION; AMINATION; ALKYNES;

D O I：

10.1007/s11426-023-1735-x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Radical-polar crossover (RPC) reaction bridges the gap between one- and two-electron reactivities, thus providing an ideal solution to overcome the limitations of both radical and polar chemistry. In this manifold, organic electrochemistry provides a uniquely facile strategy to access a diverse array of radical intermediates, thus broadening the chemical space of the RPC concept. This review highlights the synthetic advances in the field of electrochemical RPC reactions since 2020, with an emphasis on the substrate scope, reaction limitation and mechanistic aspect. The related RPC reactions are categorized as net-oxidative, net-reductive, or redox neutral transformations.

引用

页码：450 / 470

页数：21

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