Drastically reduced thermal conductivity of self-bundled single-walled carbon nanotube

被引:9
作者
Feng, Ya [1 ]
Sato, Yuta [2 ]
Inoue, Taiki [3 ]
Liu, Ming [1 ]
Chiashi, Shohei [1 ]
Xiang, Rong [1 ,5 ]
Suenaga, Kazu [4 ]
Maruyama, Shigeo [1 ]
机构
[1] Univ Tokyo, Sch Engn, Dept Mech Engn, Tokyo 1138656, Japan
[2] Natl Inst Adv Ind Sci & Technol, Nanomat Res Inst, Tsukuba 3058565, Japan
[3] Osaka Univ, Grad Sch Engn, Dept Appl Phys, Osaka 5650871, Japan
[4] Osaka Univ, Inst Sci & Ind Res, Osaka 5650871, Japan
[5] Zhejiang Univ, Sch Mech Engn, State Key Lab Fluid Power & Mechatron Syst, Hangzhou 310027, Peoples R China
基金
奥地利科学基金会;
关键词
Thermal conductivity; Single -walled carbon nanotube; Self; -bundling; Raman spectroscopy; MOLECULAR-DYNAMICS SIMULATION; TEMPERATURE-DEPENDENCE; HEAT-CONDUCTION; RAMAN-SPECTRA; PHOTOLUMINESCENCE; CHIRALITY;
D O I
10.1016/j.carbon.2022.09.024
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An individual single-walled carbon nanotube was taking U-turns and joining itself during growth, forming two distinguishable suspended sections across the slits on transmission electron microscope grid: the isolated nanotube and the self-bundled nanotube (three-nanotube bundle of the same chirality). This special formation provides the perfect specimen to study the bundling effect on various properties of carbon nanotubes. The most striking effect we elaborate on here is the drastically reduced thermal conductivity of this individual single -walled carbon nanotube after its self-bundling. The estimated thermal conductivity of the isolated nanotube is in the order of (3 -4) x 103 Wm- 1K-1, but under the heating of the same laser power, the center temperature rise of the suspended nanotube was increasing from around 150 K to about 600 K, resulting in more than 75% reduction of thermal conductivity of the self-bundled nanotube.
引用
收藏
页码:433 / 438
页数:6
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