Organoruthenium Complexes Containing Phosphinodicarboxamide Ligands

被引：0

作者：

Nolla-Saltiel, Roberto ^{[1
,2
]}

Geer, Ana M. ^{[1
,3
]}

Sharpe, Helen R. ^{[1
]}

Huke, Cameron D. ^{[1
]}

Taylor, Laurence J. ^{[1
]}

Linford-Wood, Thomas G. ^{[1
]}

James, Ashleigh ^{[1
]}

Allen, Jamie ^{[1
]}

Lewis, William ^{[1
,4
,5
]}

Blake, Alexander J. ^{[1
]}

Mcmaster, Jonathan ^{[1
]}

Kays, Deborah L. ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Univ Pk, Nottingham NG7 2RD, England

[2] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada

[3] Univ Zaragoza, CSIC, Inst Sintesis Quim & Catalisis Homogenea ISQCH, Dept Quim Inorgan, Pedro Cerbuna 12, Zaragoza 50009, Spain

[4] Univ Sydney, Sch Chem, F11 Eastern Ave, Sydney, NSW 2006, Australia

[5] Univ Sydney, Sydney Analyt, F09 Eastern Ave, Sydney, NSW 2006, Australia

来源：

INORGANICS | 2023年 / 11卷 / 09期

基金：

英国工程与自然科学研究理事会;

关键词：

phosphinocarboxamide; metallacycle; ruthenium; P ligands; coordination chemistry; X-RAY-STRUCTURE; COORDINATION CHEMISTRY; TRANSFER HYDROGENATION; PHOSPHINECARBOXAMIDE; CUMULENYLIDENE; APPROXIMATION; ALLENYLIDENE; ENERGY;

D O I：

10.3390/inorganics11090372

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ruthenium complexes of phosphinocarboxamide ligands, and their use to form metallacycles using halide abstraction/deprotonation reactions are reported. Thus, [Ru(p-cym){PPh2C(=O)NHR}Cl2; R = iPr (1), Ph (2), p-tol (3)] and [Ru(p-cym){PPh2C(=O)N(R)C(=O)N(H)R}Cl2; R = Ph (4), p-tol (5)] were synthesized from [(p-cym)RuCl2]2 (p-cym = para-cymene) and phosphinocarboxamides or phosphinodicarboxamides, respectively. Single-crystal X-ray diffraction measurements on 1-5 reveal coordination to ruthenium through the phosphorus donor, with an intramolecular hydrogen bond between the amine-bound proton and a metal-bound chloride. Six-membered metallacycles formed by halide abstraction/deprotonation of complexes 4 and 5 afforded [Ru(p-cym){& kappa;2-P,N-PPh2C(=O)N(R)C(=O)NR}Cl] [R = Ph (6), p-tol (7)]. These species exist as a mixture of two rotational isomers in solution, as demonstrated by NMR spectroscopy.

引用

页数：12

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