Crosslinked polymer electrolyte constructed by metal-oxo clusters for solid lithium metal batteries

被引：17
|
作者：
Zheng, Ying [1 ,2 ]
Wang, Chaozhi [1 ,2 ]
Zhang, Rongrong [1 ,2 ]
Dai, Shuqi [1 ,2 ]
Xie, Hao [1 ,2 ]
Cui, Jingqin [1 ,2 ]
Fang, Xiaoliang [1 ,2 ,3 ]
机构：
[1] Xiamen Univ, Pen Tung Sah Inst Micronano Sci & Technol, State Key Lab Phys Chem Solid Surfaces Collaborat, Natl & Local Joint Engn Res Ctr Preparat Technol N, Xiamen 361005, Fujian, Peoples R China
[2] Xiamen Univ, Coll Chem & Chem Engn, Xiamen 361005, Fujian, Peoples R China
[3] Fujian Sci & Technol Innovat Lab Energy Mat China, Xiamen 361005, Fujian, Peoples R China
来源：
ENERGY STORAGE MATERIALS | 2023年 / 57卷
关键词：
Lithium metal anodes; Lithium metal batteries; Nickel -rich layered oxide cathodes; Metal-oxo clusters; Crosslinked polymer electrolytes; HIGH IONIC-CONDUCTIVITY; WINDOW; CHAIN; ANODE;
D O I：
10.1016/j.ensm.2023.02.037
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
By using structurally well-defined metal-oxo clusters as crosslinkable nanofillers, the authors develop a hybrid inorganic/organic crosslinked polymer electrolyte. With the favorable electrochemical and mechanical properties, as well as the enhanced lithium dendrite-suppressing capability, the metal-oxo cluster crosslinked polymer electrolyte can significantly improve the capacities, rate capabilities, and cycling stabilities of solid lithium metal batteries. [Formula presented] © 2023 Elsevier B.V.
引用
收藏
页码：540 / 548
页数：9
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