Enhancing the Fuel Properties of Spent Coffee Grounds through Hydrothermal Carbonization: Output Prediction and Post-Treatment Approaches

The reuse potential for the large annual production of spent coffee grounds (SCGs) is underexploited in most world regions. Hydrochars from SCGs produced via hydrothermal carbonization (HTC) have been recognized as a promising solid fuel alternative. To increase demand, optimization of the HTC and two post-treatment processes, washing and agglomeration, were studied to improve hydrochar in terms of energetic properties, minimizing unwanted substances, and better handling. HTC experiments at three scales (1-18.75 L) and varying process conditions (temperature T (160-250 degrees C), reaction time t (1-5 h), and solid content %S-o (6-20%) showed that the higher heating value (HHV) can be improved by up to 46%, and most potential emissions of trace elements from combustion reduced (up to 90%). The HTC outputs (solid yield-SY, HHV, energy yield-EY) were modeled and compared to published genetic programming (GP) models. Both model types predicted the three outputs with low error (<15%) and can be used for process optimization. The efficiency of water washing depended on the HTC process temperature and type of aromatics produced. The furanic compounds were removed (69-100%; 160 degrees C), while only 34% of the phenolic compounds (240 degrees C) were washed out. Agglomeration of both wet SCG and its hydrochar is feasible; however, the finer particles of washed hydrochar (240 degrees C) resulted in larger-sized spherical pellets (85% > 2000-4000 mu m) compared to SCGs (only 4%).