CO2 Decomposition in Microwave Discharge Created in Liquid Hydrocarbon

被引:7
作者
Batukaev, Timur S. [1 ]
Bilera, Igor V. [1 ]
Krashevskaya, Galina V. [1 ,2 ]
Lebedev, Yuri A. [1 ]
Nazarov, Nurlan A. [1 ]
机构
[1] Russian Acad Sci TIPS RAS, AV Topchiev Inst Petrochem Synth, Leninsky Ave 29, Moscow 119991, Russia
[2] Natl Res Nucl Univ MEPhI, LAPLAZ, Kashirskoe Shosse 31, Moscow 115409, Russia
基金
俄罗斯科学基金会;
关键词
microwave discharge in liquid hydrocarbons; CO2; decomposition; chromatography of discharge products; optical emission spectroscopy; shadow photograph; hydrogen production; CARBON-DIOXIDE UTILIZATION; METHANE CONVERSION; PLASMA; CATALYSIS; TECHNOLOGY; REACTOR; ENERGY;
D O I
10.3390/plasma6010010
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
The task of CO2 decomposition is one of the components of the problem associated with global warming. One of the promising directions of its solution is the use of low-temperature plasma. For these purposes, different types of discharges are used. Microwave discharge in liquid hydrocarbons has not been studied before for this problem. This paper presents the results of a study of microwave discharge products in liquid Nefras C2 80/120 (petroleum solvent, a mixture of light hydrocarbons with a boiling point from 33 to 205 degrees C) when CO2 is introduced into the discharge zone, as well as the results of a study of the discharge by optical emission spectroscopy and shadow photography methods. The main gas products are H-2, C2H2, C2H4, CH4, CO2, and CO. No oxygen was found in the products. The mechanisms of CO2 decomposition in the discharge are considered. The formation of H-2 occurs simultaneously with the decomposition of CO2 in the discharge, with a volumetric rate of up to 475 mL/min and energy consumption of up to 81.4 NL/kWh.
引用
收藏
页码:115 / 126
页数:12
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