共 40 条
CO2 Decomposition in Microwave Discharge Created in Liquid Hydrocarbon
被引:7
作者:
Batukaev, Timur S.
[1
]
Bilera, Igor V.
[1
]
Krashevskaya, Galina V.
[1
,2
]
Lebedev, Yuri A.
[1
]
Nazarov, Nurlan A.
[1
]
机构:
[1] Russian Acad Sci TIPS RAS, AV Topchiev Inst Petrochem Synth, Leninsky Ave 29, Moscow 119991, Russia
[2] Natl Res Nucl Univ MEPhI, LAPLAZ, Kashirskoe Shosse 31, Moscow 115409, Russia
来源:
基金:
俄罗斯科学基金会;
关键词:
microwave discharge in liquid hydrocarbons;
CO2;
decomposition;
chromatography of discharge products;
optical emission spectroscopy;
shadow photograph;
hydrogen production;
CARBON-DIOXIDE UTILIZATION;
METHANE CONVERSION;
PLASMA;
CATALYSIS;
TECHNOLOGY;
REACTOR;
ENERGY;
D O I:
10.3390/plasma6010010
中图分类号:
O35 [流体力学];
O53 [等离子体物理学];
学科分类号:
070204 ;
080103 ;
080704 ;
摘要:
The task of CO2 decomposition is one of the components of the problem associated with global warming. One of the promising directions of its solution is the use of low-temperature plasma. For these purposes, different types of discharges are used. Microwave discharge in liquid hydrocarbons has not been studied before for this problem. This paper presents the results of a study of microwave discharge products in liquid Nefras C2 80/120 (petroleum solvent, a mixture of light hydrocarbons with a boiling point from 33 to 205 degrees C) when CO2 is introduced into the discharge zone, as well as the results of a study of the discharge by optical emission spectroscopy and shadow photography methods. The main gas products are H-2, C2H2, C2H4, CH4, CO2, and CO. No oxygen was found in the products. The mechanisms of CO2 decomposition in the discharge are considered. The formation of H-2 occurs simultaneously with the decomposition of CO2 in the discharge, with a volumetric rate of up to 475 mL/min and energy consumption of up to 81.4 NL/kWh.
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页码:115 / 126
页数:12
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