Efficient and complete dehydrogenation of hydrazine borane over a CoPt catalyst

被引：7

作者：

Wu, Haochong ^{[1
]}

Yao, Qilu ^{[1
]}

Hu, Chenxi ^{[1
]}

Long, Jianjun ^{[1
]}

Zhou, Yuanlan ^{[2
]}

Lu, Zhang-Hui ^{[1
]}

机构：

[1] Jiangxi Normal Univ, Inst Adv Mat IAM, Key Lab Energy Catalysis & Convers Nanchang, Coll Chem & Chem Engn, Nanchang 330022, Peoples R China

[2] Jiangxi Normal Univ, Sch Math & Stat, Nanchang 330022, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 81期

关键词：

COMPLETE HYDROGEN GENERATION; NANOPARTICLES; METHANOLYSIS; HYDROLYSIS;

D O I：

10.1039/d3cc03568a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bimetallic CoPt alloy nanoparticles (NPs) immobilized on CeO2 nanorods (CoPt/CeO2) were synthesized by a facile wet-chemistry reduction method, which showed the highest catalytic efficiency reported to date for the complete dehydrogenation of hydrazine borane with a high TOF value of up to 5454 h-1 at 323 K. CeO2-supported CoPt NPs were synthesized via a simple and green wet-chemistry reduction method and used as robust catalysts for complete hydrogen production from hydrazine borane.

引用

页码：12116 / 12119

页数：4

共 28 条

[1] Controlling catalytic dehydrogenation of formic acid over low-cost transition metal-substituted AuPd nanoparticles immobilized by functionalized metal-organic frameworks at room temperature [J].

Cheng, Jia ;

Gu, Xiaojun ;

Liu, Penglong ;

Wang, Tianshu ;

Su, Haiquan .

JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (42) :16645-16652

[2] Nickel- and platinum-containing core@shell catalysts for hydrogen generation of aqueous hydrazine borane [J].

Clemencon, D. ;

Petit, J. F. ;

Demirci, U. B. ;

Xu, Q. ;

Miele, P. .

JOURNAL OF POWER SOURCES, 2014, 260 :77-81

[3] High-extent dehydrogenation of hydrazine borane N2H4BH3 by hydrolysis of BH3 and decomposition of N2H4 [J].

Hannauer, Julien ;

Akdim, Ouardia ;

Demirci, Umit B. ;

Geantet, Christophe ;

Herrmann, Jean-Marie ;

Miele, Philippe ;

Xu, Qiang .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3355-3358

[4] Hydrogen carriers [J].

He, Teng ;

Pachfule, Pradip ;

Wu, Hui ;

Xu, Qiang ;

Chen, Ping .

NATURE REVIEWS MATERIALS, 2016, 1 (12)

[5] Nitrogen-functionalized carbon nanotube-supported bimetallic PtNi nanoparticles for hydrogen generation from hydrous hydrazine [J].

Hu, Xiaoping ;

Liu, Tong ;

Zhang, Xiaoli ;

Tian, Jian .

CHEMICAL COMMUNICATIONS, 2021, 57 (67) :8324-8327

[6] Catalytic methanolysis and hydrolysis of hydrazine-borane with monodisperse Ru NPs@nano-CeO2 catalyst for hydrogen generation at room temperature [J].

Karatas, Yasar ;

Gulcan, Mehmet ;

Sen, Fatih .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (26) :13432-13442

[7] Synthesis of supported Ni@(RhNi-alloy) nanocomposites as an efficient catalyst towards hydrogen generation from N2H4BH3 [J].

Li, Changming ;

Dou, Yibo ;

Liu, Jie ;

Chen, Yudi ;

He, Shan ;

Wei, Min ;

Evans, David G. ;

Duan, Xue .

CHEMICAL COMMUNICATIONS, 2013, 49 (85) :9992-9994

[8] Complete Dehydrogenation of N2H4BH3 over Noble-Metal-Free Ni0.5Fe0.5-CeOx/MIL-101 with High Activity and 100% H2 Selectivity [J].

Li, Si-Jia ;

Wang, Hong-Li ;

Wulan, Ba-Ri ;

Zhang, Xin-bo ;

Yan, Jun-Min ;

Jiang, Qing .

ADVANCED ENERGY MATERIALS, 2018, 8 (21)

[9] Advanced Electrocatalysis for Energy and Environmental Sustainability via Water and Nitrogen Reactions [J].

Li, Yi ;

Wang, Huanhuan ;

Priest, Cameron ;

Li, Siwei ;

Xu, Ping ;

Wu, Gang .

ADVANCED MATERIALS, 2021, 33 (06)

[10] Asymmetric Coordination of Single-Atom Co Sites Achieves Efficient Dehydrogenation Catalysis [J].

Liu, Hu ;

Lei, Qian ;

Miao, Ruoyan ;

Sun, Mingzi ;

Qin, Chuanjian ;

Zhang, Liang ;

Ye, Gan ;

Yao, Yao ;

Huang, Bolong ;

Ma, Zhenhui .

ADVANCED FUNCTIONAL MATERIALS, 2022, 32 (43)

← 1 2 3 →