Adsorption characteristics of amphiphilic open-cell poly(butylene succinate) foams with ultrahigh porosity

被引:10
作者
Zhu, Min [1 ]
Wei, Xinyi [1 ]
Zhang, Meng [1 ]
Zhou, Hongfu [1 ,2 ]
Wang, Xiangdong [1 ,2 ]
Hu, Jing [2 ]
机构
[1] Beijing Technol & Business Univ, Coll Chem & Mat Engn, Key Lab Proc Applicat Polymer Foams China Natl Lig, Beijing 100048, Peoples R China
[2] Beijing Technol & Business Univ, Sch Mat Sci & Mech Engn, Beijing Key Lab Qual Evaluat Technol Hyg & Safety, Beijing 100048, Peoples R China
关键词
Poly(butylene succinate); Chain extension; Open -cell foam; High adsorption; Amphiphilic; RHEOLOGICAL PROPERTIES; POLY(LACTIC ACID); DOMESTIC SEWAGE; SUPERCRITICAL CO2; CRYSTALLIZATION; BEHAVIOR; POLYPROPYLENE; EXPANSION; STATE; PARAMETERS;
D O I
10.1016/j.supflu.2023.106002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, a CO2-assisted and environmentally friendly foaming approach was proposed to prepare amphi-philic open-cell poly(butylene succinate) (PBS)/glycerin monostearate (GMS)/chain extender (CE) foams with excellent adsorption capabilities and superhigh porosity. Compared with the torqued PBS foam, the hydrophi-licity and cell stability of the PBS/GMS foam were markedly enhanced. With the gradual incorporation of CE, the crystallization temperature of diverse PBS/GMS/CE specimens increased from 79.2 degrees C to 92.1 degrees C, and their storage modulus rose by three orders of magnitude. When the CE content was 0.9 phr, the open-cell content of the PBS/GMS/CE3 foam reached 97.11 +/- 0.67%. In addition, the adsorption capacity of PBS/GMS/CE3 foam was up to 34.33 +/- 1.22 g/g for carbon tetrachloride, and its contact angle of water was 79.45 degrees. To summarize, this study provided a promising strategy for fabricating multifunctional open-cell biodegradable polymer foams that could be applicable to wastewater treatment as well as filtration.
引用
收藏
页数:13
相关论文
共 63 条
[61]   Porous carbon nanospheres aerogel based molecularly imprinted polymer for efficient phenol adsorption and removal from wastewater [J].
Zhang, Juncheng ;
Qin, Lei ;
Yang, Yongzhen ;
Liu, Xuguang .
SEPARATION AND PURIFICATION TECHNOLOGY, 2021, 274
[62]   Porous Polyethylene Bundles with Enhanced Hydrophobicity and Pumping Oil-Recovery Ability via Skin-Peeling [J].
Zhang, Xudong ;
Wang, Xiaolong ;
Liu, Xianhu ;
Lv, Cunjing ;
Wang, Yaming ;
Zheng, Guoqiang ;
Liu, Hu ;
Liu, Chuntai ;
Guo, Zhanhu ;
Shen, Changyu .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (10) :12580-12585
[63]   Hydrophobically modified chitin/halloysite nanotubes composite sponges for high efficiency oil-water separation [J].
Zhao, Xiujuan ;
Luo, Yangyang ;
Tan, Peixin ;
Liu, Mingxian ;
Zhou, Changren .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2019, 132 :406-415