The thermal decomposition of calcium propionate, in inert and oxidative atmospheres, has been investigated by thermogravimetry combined with infrared evolved gas analysis; the main volatiles formed during thermal decomposition have been identified. The intermediate and final products have been characterized by infrared spectroscopy, x-ray diffraction, elemental analysis and scanning electron microscopy. The different mechanisms involved in thermal decomposition are discussed as a function of atmosphere and sample structure. The kinetics of the decomposition and the ability of powders to undergo a thermal runaway are also investigated.
机构:
Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
Henan Univ, Lab Special Functionary Mat, Kaifeng 475001, Peoples R China
Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R ChinaChinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
Song, Meirong
Chen, Miao
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机构:
Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R ChinaChinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
Chen, Miao
Zhang, Zhijun
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Henan Univ, Lab Special Functionary Mat, Kaifeng 475001, Peoples R ChinaChinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China