Coral-like carbon skeleton for aqueous zinc-ion batteries MnO2 cathode material

被引:6
作者
Wei, Yanan [1 ]
Li, Siqi [1 ]
Wu, Qiong [1 ]
Han, Yuan [1 ]
Liu, Jiaming [2 ]
Qian, Guixiang [1 ]
Yang, Chao [1 ]
机构
[1] Anhui Polytech Univ, Sch Chem & Environm Engn, Anhui Lab Clean Energy Mat & Chem Sustainable Conv, Wuhu 241000, Peoples R China
[2] Jiangxi Univ Sci & Technol, Fac Mat Met & Chem, Ganzhou 341000, Peoples R China
关键词
Aqueous zinc-ion batteries; MnO2; Mesoporous carbon; Electrochemistry; ELECTROCHEMICAL PERFORMANCE; HIGH-CAPACITY; TIO2; ANATASE; STORAGE; ELECTROLYTE;
D O I
10.1007/s11581-023-05149-x
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Rechargeable aqueous zinc-ion batteries (AZIBs) have attracted significant attention in the field of energy storage due to their high theoretical capacity, low toxicity, excellent safety performance, low cost, and affordability. As the cathode material of AZIBs, MnO2 boasts advantages such as cost-effectiveness and low environmental impact. However, it still exhibits certain limitations such as inadequate conductivity and compromised structural stability. In this work, a coral-like carbon skeleton (CCS) was designed to stabilize the electrochemical properties of the MnO2 cathode by growing the MnO2 on the surface of CCS. It is found that CCS@MnO2 exhibits notable advantages in terms of stable cycling performance and high specific capacity. This material exhibits an approximate 100% coulombic efficiency after 500 cycles when subjected to a current density of 1.0 A g(-1). The CCS support significantly enhanced the performance of AZIBs and rendering it highly appealing for diverse range of energy applications.
引用
收藏
页码:4733 / 4741
页数:9
相关论文
共 39 条
[1]   Electrochemically Induced Structural Transformation in a γ-MnO2 Cathode of a High Capacity Zinc-Ion Battery System [J].
Alfaruqi, Muhammad H. ;
Mathew, Vinod ;
Gim, Jihyeon ;
Kim, Sungjin ;
Song, Jinju ;
Baboo, Joseph P. ;
Choi, Sun H. ;
Kim, Jaekook .
CHEMISTRY OF MATERIALS, 2015, 27 (10) :3609-3620
[2]   A high surface area tunnel-type α-MnO2 nanorod cathode by a simple solvent-free synthesis for rechargeable aqueous zinc-ion batteries [J].
Alfaruqi, Muhammad Hilmy ;
Islam, Saiful ;
Gim, Jihyeon ;
Song, Jinju ;
Kim, Sungjin ;
Duong Tung Pham ;
Jo, Jeonggeun ;
Xiu, Zhiliang ;
Mathew, Vinod ;
Kim, Jaekook .
CHEMICAL PHYSICS LETTERS, 2016, 650 :64-68
[3]   Enhanced reversible divalent zinc storage in a structurally stable α-MnO2 nanorod electrode [J].
Alfaruqi, Muhammad Hilmy ;
Gim, Jihyeon ;
Kim, Sungjin ;
Song, Jinju ;
Jo, Jeonggeun ;
Kim, Seokhun ;
Mathew, Vinod ;
Kim, Jaekook .
JOURNAL OF POWER SOURCES, 2015, 288 :320-327
[4]   Porous cube-like Mn3O4@C as an advanced cathode for low-cost neutral zinc-ion battery [J].
Chen, Hui ;
Zhou, Wanhai ;
Zhu, Ding ;
Liu, Zhenzhen ;
Feng, Zhao ;
Li, Jinchi ;
Chen, Yungui .
JOURNAL OF ALLOYS AND COMPOUNDS, 2020, 813
[5]   Advanced electrochemical performance of ZnMn2O4/N-doped graphene hybrid as cathode material for zinc ion battery [J].
Chen, Linlin ;
Yang, Zhanhong ;
Qin, Haigang ;
Zeng, Xiao ;
Meng, Jinlei .
JOURNAL OF POWER SOURCES, 2019, 425 :162-169
[6]   Structural in Situ Study of the Thermal Behavior of Manganese Dioxide Materials: Toward Selected Electrode Materials for Supercapacitors [J].
Ghodbane, Ouassim ;
Pascal, Jean-Louis ;
Fraisse, Bernard ;
Favier, Frederic .
ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (12) :3493-3505
[7]   A case study of β- and δ-MnO2 with different crystallographic forms on ion-storage in rechargeable aqueous zinc ion battery [J].
Guo, Cong ;
Zhou, Qihao ;
Liu, Huimin ;
Tian, Shuo ;
Chen, Binglei ;
Zhao, Jian ;
Li, Jingfa .
ELECTROCHIMICA ACTA, 2019, 324
[8]   Cathode Interfacial Layer Formation via in Situ Electrochemically Charging in Aqueous Zinc-Ion Battery [J].
Guo, Shan ;
Liang, Shuquan ;
Zhang, Baoshan ;
Fang, Guozhao ;
Ma, Dan ;
Zhou, Jiang .
ACS NANO, 2019, 13 (11) :13456-13464
[9]   Zn/MnO2 battery chemistry with dissolution-deposition mechanism [J].
Guo, Xun ;
Zhou, Jiang ;
Bai, Chaolei ;
Li, Xinkuo ;
Fang, Guozhao ;
Liang, Shuquan .
MATERIALS TODAY ENERGY, 2020, 16
[10]   Consecutive core-shell SP@PDA-d-δ-MnO2 cathode material for aqueous zinc-ion batteries [J].
Han, Yuan ;
Wu, Qiong ;
Li, Siqi ;
Ding, Qiangwei ;
Cao, Yong ;
Gao, Yuanyuan ;
Liu, Rongmei ;
Wang, Tao ;
Tian, Zhongliang ;
Yang, Chao .
JOURNAL OF ALLOYS AND COMPOUNDS, 2023, 938