Removal of chromium (VI) by commercial anion exchange membrane BII from an aqueous solution: Adsorption kinetic, equilibrium and thermodynamic studies

被引：21

作者：

Arif, Sadaf ^{[1
]}

Zafar, Shagufta ^{[1
]}

Khan, Muhammad Imran ^{[2
]}

Manzoor, Suryyia ^{[3
]}

Shanableh, Abdallah ^{[2
]}

Garcia, Javier Fernandez ^{[4
,5
]}

Hayat, Muhammad ^{[3
]}

机构：

[1] Govt Sadiq Coll Women Univ, Dept Chem, Bahawalpur 63000, Pakistan

[2] Univ Sharjah, Res Inst Sci & Engn RISE, Sharjah 27272, U Arab Emirates

[3] Bahauddin Zakariya Univ, Inst Chem Sci, Multan 60800, Pakistan

[4] UCL, Dept Chem Engn, Torrington Pl, London WC1E 7JE, England

[5] Univ Ramon Llull, IQS Sch Engn, Via Augusta 390, Barcelona 08017, Spain

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2023年 / 152卷

关键词：

Chromium; Anion exchange membrane BII; Endothermic process; Adsorption; Pseud-second-order model; CONGO RED-DYE; ACTIVATED CARBON; METHYL-ORANGE; RICE HUSK; ADSORBENT; LEAVES; IONS; BPPO; WASTEWATERS; SORBENT;

D O I：

10.1016/j.inoche.2023.110696

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This work reports chromium (Cr(VI)) adsorption from an aqueous solution onto anion exchange membrane (AEM) BII. The Cr(VI) percentage adsorption was increased from 71 to 82 %, 70 to 92 % and 72 to 86 % with BII membrane dosage, contact time, and temperature respectively while decrease 93 to 84 % with Cr(VI) initial concentration. Kinetic illustration showed that Cr(VI) adsorption obeyed pseud-second-order model. Isotherm illustration denoted that Cr(VI) adsorption onto BII membrane fitted to Langmuir isotherm because correlation coefficient (R2 = 0.992) was close to unity. Moreover, determined mean adsorption energy (E = 2.78 KJ/mol) value represented that Cr(VI) adsorption onto BII membranes was physical adsorption process. Measured value of enthalpy (Delta H degrees = 13.59 KJ/mol) suggested that it was endothermic process. In addition, the determined of Gibb's free energy (Delta G degrees) value for Cr (VI) adsorption revealed that it was spontaneous and feasible process.

引用

页数：9

共 61 条

[61] Adsorption of chromium (VI) from aqueous solution by the iron (III)-impregnated sorbent prepared from sugarcane bagasse [J].

Zhu, Y. ;

Zhang, H. ;

Zeng, H. ;

Liang, M. ;

Lu, R. .

INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY, 2012, 9 (03) :463-472

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