Rapid and sensitive colorimetric detection of ascorbic acid using carboxymethyl cellulose functionalized Co3O4 nanoparticles as peroxidase mimic

被引：1
作者：
Tiwari, Puneet [1 ]
Malviya, Tulika [1 ]
Singh, Vandana [1 ]
机构：
[1] Univ Allahabad, Dept Chem, Prayagraj 211002, India
来源：
CHEMICAL PAPERS | 2023年 / 77卷 / 09期
关键词：
Carboxymethyl cellulose; Co3O4; Nanoparticles; Ascorbic acid; Sensing; MIMETIC ACTIVITY; THERMAL-DECOMPOSITION; LIQUID-CHROMATOGRAPHY; OXIDE NANOPARTICLES; GREEN SYNTHESIS; GRAPHENE OXIDE; H2O2; NANOCOMPOSITES; GLUCOSE; NANOFLAKES;
D O I：
10.1007/s11696-023-02876-3
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Herein we demonstrate the synthesis, characterization, and peroxidase-mimicking behavior of carboxymethyl cellulose-Co3O4 nanoparticles (C@NZ(3)) toward rapid and sensitive colorimetric detection of ascorbic acid (AA). AA was detected by monitoring the quenching of color signal that was obtained from C@NZ(3) catalyzed H2O2 oxidation of 3,3 & PRIME;,5,5 & PRIME;-tetramethylbenzidine (TMB). The excellent peroxidase-mimicking behavior of C@NZ(3) is evidenced by the low detection limit of AA (0.41 & mu;M) and good linearity in the range of 0.5-30 & mu;M. The method is cost-effective, highly selective, and requires only 3 min to complete. C@NZ(3) exhibited high shelf life and could be successfully used to detect AA in real samples of human serum.
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收藏
页码：5441 / 5453
页数：13
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