Synthetic hureaulite as anode material for lithium-ion batteries

被引：6
作者：
Pan, Meng-Yao [1 ]
Lu, Si-Tong [1 ]
Li, Yan-Yan [1 ]
Fan, Yang [1 ]
机构：
[1] Xinyang Normal Univ, Coll Chem & Chem Engn, Xinyang, Peoples R China
来源：
JOURNAL OF APPLIED ELECTROCHEMISTRY | 2023年 / 53卷 / 05期
基金：
中国国家自然科学基金;
关键词：
Lithium-ion batteries; Hureaulite; Manganese phosphate; Anode materials; Electrochemical performance; NEXT-GENERATION; RECHARGEABLE LITHIUM; ENERGY-STORAGE; PERFORMANCE; ELECTRODE;
D O I：
10.1007/s10800-022-01831-6
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The synthetic hureaulite with the formula Mn-5(HOPO3)(2)(PO4)(2)(H2O)(4) (abbreviated as MHPH) was obtained under mild hydrothermal conditions. Crystal structure characterization shows that MHPH has a three-dimensional open-framework structure. The electrochemical performance of MHPH as anode material for lithium-ion batteries (LIBs) was investigated. MHPH delivers a capacity of 778.7 mAh g(-1) at 0.1 A g(-1) and long-term cycling stability over 2000 cycles at 2.0 A g(-1). The electrochemical kinetics analysis indicates that lithium storage of the MHPH anode involves both the diffusion-controlled insertion process and the contribution from surface capacitive effect. This kind of multiple energy storage mode leads to good lithium storage performance of the synthetic hureaulite.
引用
收藏
页码：1015 / 1022
页数：8
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