Photothermal Conversion Porous Organic Polymers: Design, Synthesis, and Applications

被引：29
作者：
Shi, Yu [1 ]
Wang, Yuzhu [1 ]
Meng, Nan [1 ]
Liao, Yaozu [1 ]
机构：
[1] Donghua Univ, Coll Mat Sci & Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China
来源：
SMALL METHODS | 2024年 / 8卷 / 10期
基金：
上海市自然科学基金; 中国国家自然科学基金;
关键词：
photothermal catalysis and latent heat storage; phototherapeutic and drug delivery; porous organic polymers; solar evaporation and desalination; structural design; CONJUGATED MICROPOROUS POLYMER; POWER-GENERATION; LATENT-HEAT; MEMBRANES; WATER; FRAMEWORKS; PORPHYRIN; STORAGE; EFFICIENCY; MANAGEMENT;
D O I：
10.1002/smtd.202301554
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Solar energy is a primary form of renewable energy, and photothermal conversion is a direct conversion process with tunable conversion efficiency. Among various kinds of photothermal conversion materials, porous organic polymers (POP) are widely investigated owing to their controllable molecular design, tailored porous structures, good absorption of solar light, and low thermal conductivity. A variety of POP, such as conjugated microporous polymers (CMP), covalent organic frameworks (COF), hyper-crosslinked porous polymers (HCP), polymers of intrinsic microporosity (PIM), porous ionic polymers (PIP), are developed and applied in photothermal conversion applications of seawater desalination, latent energy storage, and biomedical fields. In this review, a comprehensive overview of the recent advances in POP for photothermal conversion is provided. The micro molecular structure characteristics and macro morphology of POP are designed for applications such as seawater desalination, latent heat energy storage, phototherapy and photodynamic therapy, and drug delivery. Besides, a probe into the underlying mechanism of structural design for constructing POP with excellent photothermal conversion performance is methodicalized. Finally, the remaining challenges and prospective opportunities for the future development of POP for solar energy-driven photothermal conversion applications are elucidated. This review comprehensively summarizes the structural design, categories, and applications of porous organic polymers (POP) in photothermal conversion. The engineering strategies of micro molecular structure and macro morphology are discussed for multidimensional construction of applications such as seawater desalination, latent heat energy storage, phototherapy and photodynamic therapy, and drug delivery. Finally, the promising directions are presented to provide enlightenment for high-performance photothermal responsive POP materials. image
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页数：26
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