Peripheral nucleic bases boost H2 production by synthetic molecular catalysts in acidic water

被引：9

作者：

Das, Srewashi ^{[1
]}

Das, Chandan ^{[1
]}

Shah, Naseer Ahmad ^{[1
]}

Ghorai, Santanu ^{[1
]}

Majumder, Piyali ^{[2
]}

Dutta, Arnab ^{[1
,2
,3
]}

机构：

[1] Indian Inst Technol, Chem Dept, Powai 400076, Maharashtra, India

[2] Indian Inst Technol, Natl Ctr Excellence, CCU, Powai 400076, Maharashtra, India

[3] Indian Inst Technol, Interdisciplinary Program Climate Studies, Powai 400076, Maharashtra, India

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 47期

关键词：

HYDROGEN-PRODUCTION; PROTON-TRANSFER; COBALOXIMES; EVOLUTION; MODELS; SPHERE;

D O I：

10.1039/d3cc00964e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The strategic inclusion of nucleic bases adenine, cytosine, and thymine, in the form of outer coordination sphere, positively impacts the electro- and photocatalytic H-2 production by cobaloxime cores. These cobaloxime derivatives showcased their optimal H-2 production in acidic media due to specific protonation of adenine and cytosine below pH 5.0.

引用

页码：7243 / 7246

页数：4

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