Temperature and pH dual response flexible silica aerogel with switchable wettability for selective oil/water separation

被引:8
作者
He, Song [1 ]
Li, Kangwei [1 ]
Du, Chunhua [1 ]
Li, Zhiqi [1 ]
Huang, Yajun [2 ]
Cao, Chengyang [3 ]
机构
[1] Wuhan Univ Technol, Sch Safety Sci & Emergency Management, Luoshi Rd 122, Wuhan 430070, Peoples R China
[2] Nanjing Tech Univ, Coll Emergency Management, Nanjing 211816, Peoples R China
[3] Wuhan Inst Technol, Sch Resources & Safety Engn, Wuhan 430074, Peoples R China
基金
中国国家自然科学基金;
关键词
Silica aerogel; Mechanical properties; Oil/water separation; Temperature response; pH response; HIGHLY-EFFICIENT; OIL; REMOVAL;
D O I
10.1016/j.marpolbul.2023.116011
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Silica aerogels are attractive oil-absorbing agents due to their low density, high porosity. However, how to discharge the oil which adsorbed by silica aerogels is a difficult issue. To address this challenge, new separation strategies with high efficiency are needed. In this study, we prepared the temperature and pH dual response flexible silica aerogel have temperature response and pH response effect, which can change its wettability by adjusting temperature or pH. On the one hand, the temperature and pH responsive flexible silica aerogel can be used to adsorb water at the temperature below 34.73 degrees C or pH > 7. On the other hand, it can adsorb oil at a temperature above 34.73 degrees C or pH < 7. The automatic desorption of oil can be achieved without consuming additional energy and damaging the pore structure. Therefore, the sample could continuously adsorb and filtrate efficiently and realize the recovery of oil and adsorption materials.
引用
收藏
页数:14
相关论文
共 36 条
[1]  
ALEXANDER GB, 1954, J PHYS CHEM-US, V57, P932
[2]   Carbon Fiber Aerogel Made from Raw Cotton: A Novel, Efficient and Recyclable Sorbent for Oils and Organic Solvents [J].
Bi, Hengchang ;
Yin, Zongyou ;
Cao, Xiehong ;
Xie, Xiao ;
Tan, Chaoliang ;
Huang, Xiao ;
Chen, Bo ;
Chen, Fangtao ;
Yang, Qingling ;
Bu, Xinyang ;
Lu, Xuehong ;
Sun, Litao ;
Zhang, Hua .
ADVANCED MATERIALS, 2013, 25 (41) :5916-5921
[3]   Thermo and pH Dual-Responsive Materials for Controllable Oil/Water Separation [J].
Cao, Yingze ;
Liu, Na ;
Fu, Changkui ;
Li, Kan ;
Tao, Lei ;
Feng, Lin ;
Wei, Yen .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (03) :2026-2030
[4]   Thermo-Responsive Cellulose-Based Material with Switchable Wettability for Controllable Oil/Water Separation [J].
Chen, Wenbo ;
He, Hui ;
Zhu, Hongxiang ;
Cheng, Meixiao ;
Li, Yunhua ;
Wang, Shuangfei .
POLYMERS, 2018, 10 (06)
[5]   An underwater pH-responsive superoleophobic surface with reversibly switchable oil-adhesion [J].
Cheng, Qunfeng ;
Li, Mingzhu ;
Yang, Fu ;
Liu, Mingjie ;
Li, Lin ;
Wang, Shutao ;
Jiang, Lei .
SOFT MATTER, 2012, 8 (25) :6740-6743
[6]   Oil/Water Separation with Selective Superantiwetting/Superwetting Surface Materials [J].
Chu, Zonglin ;
Feng, Yujun ;
Seeger, Stefan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (08) :2328-2338
[7]   Superhydrophobic polymer-coated copper-mesh; membranes for highly efficient oil-water separation [J].
Crick, Colin R. ;
Gibbins, James A. ;
Parkin, Ivan P. .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (19) :5943-5948
[8]   Insight into ultra-flexible & robust silica aerogels based on diene synthesis reaction: Preparation and oil/water separation [J].
Du, Chunhua ;
Chen, Yue ;
He, Song ;
Ruan, Chichi ;
Liu, Xinyu ;
He, Chunxiang ;
Jin, Xin ;
Chen, Qilin ;
Ma, Yuansheng ;
Chen, Guanyu .
APPLIED SURFACE SCIENCE, 2022, 606
[9]   Theoretical study of heat transfer model of silica aerogel based on the porous structure of secondary particles [J].
He, Song ;
Zhang, Xiaoqian ;
Wu, Xiya ;
Li, Ping ;
Xu, Lei .
APPLIED THERMAL ENGINEERING, 2024, 238
[10]   Effect of heat treatment on hydrophobic silica aerogel [J].
He, Song ;
Huang, Yajun ;
Chen, Guangnan ;
Feng, Mengmeng ;
Dai, Huaming ;
Yuan, Bihe ;
Chen, Xianfeng .
JOURNAL OF HAZARDOUS MATERIALS, 2019, 362 :294-302