A Regulable Polyporous Graphite/Melamine Foam for Heat Conduction, Sound Absorption and Electromagnetic Wave Absorption

被引:76
作者
Li, Zijing [1 ]
Zhang, Limin [1 ]
Wu, Hongjing [1 ]
机构
[1] Northwestern Polytech Univ, Sch Phys Sci & Technol, MOE Key Lab Mat Phys & Chem Extraordinary, Xian 710072, Peoples R China
基金
美国国家科学基金会;
关键词
electromagnetic wave absorption; heat conductive; Melamine foam; sound absorption; HIGH-PERFORMANCE; COMPOSITES; CO3O4; BAND;
D O I
10.1002/smll.202305120
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To reduce electromagnetic interference and noise pollution within communication base stations and servers, it is necessary for electromagnetic wave absorption (EWA) materials to transition from coating to multifunctional devices. Up to now, the stable and effective integration of multiple functions into one material by a simple method has remained a large challenge. Herein, a foam-type microwave absorption device assembled with multicomponent organic matter and graphite powder is synthesized by a universal combination process. Melamine and phenolic aldehyde amine work as the skeleton and cementing compound, respectively, in which graphite is embedded in the cementing compound interconnected into the mesoscopic 3D electric conductive and heat conductive network. Interestingly, the prepared flexible graphite/melamine foam (CMF) delivers a great EWA performance, with a great effective absorption bandwidth of 9.8 GHz, ultrathin thickness of 2.60 mm, and a strong absorption reflection loss of -41.7 dB. Moreover, the CMF possesses porosity and flexibility, endowing it with sound absorption ability. The CMF is unique in its integration of EWA, heat conduction, sound absorption, and mechanical robustness, as well as its cost-effective and scalable manufacturing. These attributes make CMF promising as a multifunctional device widely used in communication base stations, servers, and chips protection. The polymer (phenolic amine) loading microwave absorbent (graphite) is assembled together on the 3D network skeleton (MF) to form a multi-functional composite foam material (CMF) that integrates electromagnetic wave absorption, heat dissipation, flexibility, and sound absorption. As a result, the CMF shows the optimum effective absorption bandwidth (EAB) of 9.8 GHz at a thickness of 2.6 mm.image
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页数:11
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