Silver(I) coordination polymers based on nitrile-functionalized mixed-donor ligands of different flexibility

被引：0

作者：

Blake, Alexander J. ^{[1
]}

Aragoni, Carla M. ^{[2
]}

Arca, Massimiliano ^{[2
]}

Caltagirone, Claudia ^{[2
]}

Garau, Alessandra ^{[2
]}

Lippolis, Vito ^{[2
]}

Picci, Giacomo ^{[2
]}

Podda, Enrico ^{[3
]}

Montis, Riccardo ^{[4
]}

机构：

[1] Univ Nottingham, Sch Chem, Univ Pk, Nottingham NG7 2RD, England

[2] Univ Studi Cagliari, Dipartimento Sci Chim & Geolog, SS 554 Bivio Sestu, I-09042 Monserrato, CA, Italy

[3] Univ Studi Cagliari, Ctr Servizi Ateneo Ric CeSAR, I-09042 Monserrato, CA, Italy

[4] Univ Urbino Carlo Bo, Dipartimento Sci Pure & Applicate, Via Aurelio Saffi 2, I-61029 Urbino, PU, Italy

来源：

INORGANICA CHIMICA ACTA | 2023年 / 556卷

关键词：

Silver(I); Macrocyles; Nitrile group; Coordination polymer; PENDANT-ARM DERIVATIVES; COMPLEXES; CHEMISTRY; CRYSTAL; MACROCYCLES; FLUORESCENT; CONSTRUCTION; CHEMOSENSORS; TRANSITION; DESIGN;

D O I：

10.1016/j.ica.2023.121648

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The nitrile-functionalized derivatives of 2,8-dithia-5-aza-2,6-pyridinophane ([12]anePyNS2)(Py = Pyridine), 1aza-4,7,10-trithiacyclododecane ([12]aneNS3), and N,N'-bis(2-pyridylmethyl)-propylenediamine (Pypn), referred to as L10, L11 and L12, respectively, have been prepared. Following the reaction of these ligands with silver(I) salts, the three coordination polymers (CPs) {[Ag(L10)](BF4)}& INFIN;, {[Ag(L11)](BF4)& BULL;1/2MeCN}& INFIN;, and {[Ag (L12)](NO3)}& INFIN;, have been isolated and structurally characterized. The structural features of the three CPs depends more on the nature of the un-functionalized ligands rather than on the presence of the nitrile groups. A comparative analysis of the structures of the three CPs is performed in relation to the structures of polymeric silver(I) compounds obtained with nitrile-functionalized pendant arms of related aza- and mixed donor macrocyclic ligands (L1-L9) reported in the literature.

引用

页数：8

共 49 条

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