From insulator to semiconductor: effect of host-guest interactions on charge transport in M-MOF-74 metal-organic frameworks

被引：6

作者：

Angel, Sydney M. ^{[1
]}

Barnett, Nicholas S. ^{[1
,2
]}

Talin, A. Alec ^{[3
]}

Foster, Michael E. ^{[3
]}

Stavila, Vitalie ^{[3
]}

Allendorf, Mark D. ^{[3
]}

So, Monica C. ^{[1
]}

机构：

[1] Calif State Univ Chico, Dept Chem & Biochem, Chico, CA 95973 USA

[2] Univ Illinois, Dept Phys, Chicago, IL 60680 USA

[3] Sandia Natl Labs, Livermore, CA 94551 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2024年 / 12卷 / 08期

基金：

美国国家科学基金会;

关键词：

ELECTRICAL-CONDUCTIVITY; ELECTRONIC DEVICES; CO2; ADSORPTION; ROADMAP; SITES; FILMS;

D O I：

10.1039/d3tc04155g

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Here, we report an air-free approach to infiltrate isostructural metal-organic frameworks (MOFs), M-MOF-74 (M = Cu, Mn, Zn, Mg), with conjugated acceptor 7,7,8,8-tetracyanoquinodimethane (TCNQ). The TCNQ@M-MOF-74 compounds exhibit a striking correlation between their bulk conductivities and the open d shell variants (Cu, Mn), arising from TCNQ p-doping of the MOFs. Importantly, conjugation of the guest molecule is a prerequisite for inducing electrical conductivity in these systems. Here, we report an air-free approach to infiltrate isostructural metal-organic frameworks (MOFs), M-MOF-74 (M = Cu, Mn, Zn, Mg), with conjugated acceptor 7,7,8,8-tetracyanoquinodimethane (TCNQ).

引用

页码：2699 / 2704

页数：7

共 50 条

[31] Biological metal-organic frameworks: Structures, host-guest chemistry and bio-applications
Cai, Hong
Huang, Yong-Liang
Li, Dan
COORDINATION CHEMISTRY REVIEWS, 2019, 378 : 207 - 221
[32] Solid-state NMR studies of host-guest chemistry in metal-organic frameworks
Xiao, Yuqing
Li, Shenhui
Xu, Jun
Deng, Feng
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2022, 61
[33] Supramolecular metal-organic frameworks as host-guest nanoplatforms for versatile and customizable biomedical applications
Hu, Qiuhui
Zhang, Bo
Ren, Huiming
Zhou, Xiaoxuan
He, Chengbin
Shen, Youqing
Zhou, Zhuxian
Hu, Hongjie
ACTA BIOMATERIALIA, 2023, 168 : 617 - 627
[34] Hybridization from Guest-Host Interactions Reduces the Thermal Conductivity of Metal-Organic Frameworks
DeCoster, Mallory E.
Babaei, Hasan
Jung, Sangeun S.
Hassan, Zeinab M.
Gaskins, John T.
Giri, Ashutosh
Tiernan, Emma M.
Tomko, John A.
Baumgart, Helmut
Norris, Pamela M.
McGaughey, Alan J. H.
Wilmer, Christopher E.
Redel, Engelbert
Giri, Gaurav
Hopkins, Patrick E.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (08) : 3603 - 3613
[35] Density Functional Theory Analysis of Host-Guest Interactions in Cu(II)-Based Metal-Organic Frameworks for Pesticide Detection
Halder, Shibashis
Barma, Arpita
Rizzoli, Corrado
Ghosh, Pritam
Roy, Partha
ACS APPLIED NANO MATERIALS, 2019, 2 (09) : 5469 - 5474
[36] Nanopore-induced host-guest charge transfer phenomena in a metal-organic framework
Yamamoto, S.
Pirillo, J.
Hijikata, Y.
Zhang, Z.
Awaga, K.
CHEMICAL SCIENCE, 2018, 9 (13) : 3282 - 3289
[37] Host-guest charge transfer for scalable single crystal epitaxy of a metal-organic framework
Mantel, Arthur
Stoeger, Berthold
Prado-Roller, Alexander
Shiozawa, Hidetsugu
COMMUNICATIONS MATERIALS, 2024, 5 (01)
[38] Epitaxial Growth of γ-Cyclodextrin-Containing Metal-Organic Frameworks Based on a Host-Guest Strategy
Shen, Dengke
Wang, Gang
Liu, Zhichang
Li, Peng
Cai, Kang
Cheng, Chuyang
Shi, Yi
Han, Ji-Min
Kung, Chung-Wei
Gong, Xirui
Guo, Qing-Hui
Chen, Hongliang
Sue, Andrew C. -H.
Botros, Youssry Y.
Facchetti, Antonio
Farha, Omar K.
Marks, Tobin J.
Stoddart, J. Fraser
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (36) : 11402 - 11407
[39] Mixed electronic-ionic conductors based on host-guest architectures of metal-organic frameworks
Luo, Jiangshui
Jia, Xu
Ren, Chongting
MATTER, 2022, 5 (03) : 772 - 774
[40] Epitaxial Growth of γ-Cyclodextrin-Containing Metal-Organic Frameworks Based on a Host-Guest Strategy
Stoddart, J. Fraser (stoddart@northwestern.edu), 1600, American Chemical Society (140):

← 1 2 3 4 5 →