From insulator to semiconductor: effect of host-guest interactions on charge transport in M-MOF-74 metal-organic frameworks

被引：6

作者：

Angel, Sydney M. ^{[1
]}

Barnett, Nicholas S. ^{[1
,2
]}

Talin, A. Alec ^{[3
]}

Foster, Michael E. ^{[3
]}

Stavila, Vitalie ^{[3
]}

Allendorf, Mark D. ^{[3
]}

So, Monica C. ^{[1
]}

机构：

[1] Calif State Univ Chico, Dept Chem & Biochem, Chico, CA 95973 USA

[2] Univ Illinois, Dept Phys, Chicago, IL 60680 USA

[3] Sandia Natl Labs, Livermore, CA 94551 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2024年 / 12卷 / 08期

基金：

美国国家科学基金会;

关键词：

ELECTRICAL-CONDUCTIVITY; ELECTRONIC DEVICES; CO2; ADSORPTION; ROADMAP; SITES; FILMS;

D O I：

10.1039/d3tc04155g

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Here, we report an air-free approach to infiltrate isostructural metal-organic frameworks (MOFs), M-MOF-74 (M = Cu, Mn, Zn, Mg), with conjugated acceptor 7,7,8,8-tetracyanoquinodimethane (TCNQ). The TCNQ@M-MOF-74 compounds exhibit a striking correlation between their bulk conductivities and the open d shell variants (Cu, Mn), arising from TCNQ p-doping of the MOFs. Importantly, conjugation of the guest molecule is a prerequisite for inducing electrical conductivity in these systems. Here, we report an air-free approach to infiltrate isostructural metal-organic frameworks (MOFs), M-MOF-74 (M = Cu, Mn, Zn, Mg), with conjugated acceptor 7,7,8,8-tetracyanoquinodimethane (TCNQ).

引用

页码：2699 / 2704

页数：7

共 37 条

[1] A Roadmap to Implementing Metal-Organic Frameworks in Electronic Devices: Challenges and Critical Directions
Allendorf, Mark D.
Schwartzberg, Adam
Stavila, Vitalie
Talin, A. Alec
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (41) : 11372 - 11388
[2] HOPPING CONDUCTIVITY IN DISORDERED SYSTEMS
AMBEGAOKAR, V
HALPERIN, BI
LANGER, JS
[J]. PHYSICAL REVIEW B-SOLID STATE, 1971, 4 (08): : 2612 - +
[3] Host-Guest Interactions in Metal-Organic Frameworks Doped with Acceptor Molecules as Revealed by Resonance Raman Spectroscopy
Blaha, Michal
Vales, Vaclav
Bastl, Zdenek
Kalbac, Martin
Shiozawa, Hidetsugu
[J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2020, 124 (44) : 24245 - 24250
[4] SOLUTION DIMERIZATION OF TETRACYANOQUINODIMETHANE ION RADICAL
BOYD, RH
PHILLIPS, WD
[J]. JOURNAL OF CHEMICAL PHYSICS, 1965, 43 (09) : 2927 - &
[5] Charge transport in metal-organic frameworks for electronics applications
Calvo, James J.
Angel, Sydney M.
So, Monica C.
[J]. APL MATERIALS, 2020, 8 (05)
[6] Metal-Organic Frameworks as Active Materials in Electronic Sensor Devices
Campbell, Michael G.
Dinca, Mircea
[J]. SENSORS, 2017, 17 (05)
[7] Metallic Conductivity in a Two-Dimensional Cobalt Dithiolene Metal-Organic Framework
Clough, Andrew J.
Skelton, Jonathan M.
Downes, Courtney A.
de la Rosa, Ashley A.
Yoo, Joseph W.
Walsh, Aron
Melot, Brent C.
Marinescu, Smaranda C.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (31) : 10863 - 10867
[8] Unraveling the Semiconducting/Metallic Discrepancy in Ni3(HITP)2
Foster, Michael E.
Sohlberg, Karl
Allendorf, Mark D.
Talin, A. Alec
[J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2018, 9 (03): : 481 - 486
[9] Proposed Modification of the Graphene Analogue Ni3(HITP)2 To Yield a Semiconducting Material
Foster, Michael E.
Sohlberg, Karl
Spataru, Catalin D.
Allendorf, Mark D.
[J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (27) : 15001 - 15008
[10] Ab Initio Derived Force Fields for Predicting CO2 Adsorption and Accessibility of Metal Sites in the Metal-Organic Frameworks M-MOF-74 (M = Mn, Co, Ni, Cu)
Haldoupis, Emmanuel
Borycz, Joshua
Shi, Huiliang
Vogiatzis, Konstantinos D.
Bai, Peng
Queen, Wendy L.
Gagliardi, Laura
Siepmann, J. Ilja
[J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (28) : 16058 - 16071

← 1 2 3 4 →