High-pressure/high-temperature synthesis of Nd3B5O11(OH)2

被引：1
作者：
Teichtmeister, Tobias A. [1 ]
Bernhart, Alexander Hugo [1 ]
Schwarzmuller, Stefan [1 ]
Wurst, Klaus [1 ]
Huppertz, Hubert [1 ]
机构：
[1] Univ Innsbruck, Dept Gen Inorgan & Theoret Chem, Innrain 80 82, A-6020 Innsbruck, Austria
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2024年 / 650卷 / 01期
关键词：
borate; high-pressure; neodymium; rare earth; solid-state chemistry; CRYSTAL-STRUCTURE; STRUCTURE VALIDATION; ND; LA; BOND; RE; SM; LN;
D O I：
10.1002/zaac.202300210
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The neodymium borate Nd3B5O11(OH)(2) was obtained from Nd2O3, B2O3, and H3BO3 by high-pressure/high-temperature synthesis at 13 GPa and 850 degrees C. Based on single-crystal diffraction data, a crystal structure in the orthorhombic space group Pnna (no. 52) with the unit cell parameters a=4.5128(1) & Aring;, b=13.3264(3) & Aring;, c=14.1882(4) & Aring;, and four formula units per cell was found. The crystal structure is built up by a framework of corner-sharing [BO4](5-) tetrahedra forming corrugated eight-, ten-, and fourteen-membered rings. Furthermore, the powder X-ray diffraction pattern and the infrared spectrum of the title compound are reported.
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页数：8
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