Evaluation of Structural Stability, Mechanical Properties, and Corrosion Resistance of Magnesia Partially Stabilized Zirconia (Mg-PSZ)

被引:11
作者
Yusuf, Dedek [1 ]
Maryani, Eneng [2 ]
Mardhian, Deby Fajar [3 ,4 ]
Noviyanti, Atiek Rostika [1 ]
机构
[1] Univ Padjadjaran, Dept Chem, Jl Raya Bandung Sumedang Km 21, Sumedang 45361, Jawa Barat, Indonesia
[2] Minist Ind Indonesia, Ctr Ceram, Jl Ahmad Yani 392, Bandung 40272, Jawa Barat, Indonesia
[3] Univ Padjadjaran, Fac Dent, Dept Dent Mat Sci & Technol, Jl Raya Bandung Sumedang Km 21, Sumedang 45363, Jawa Barat, Indonesia
[4] Univ Padjadjaran, Fac Dent, Oral Biomat Res Ctr, Jl Sekeloa Selatan I 1, Bandung 40132, Jawa Barat, Indonesia
关键词
nano-Mg-PSZ; zirconia; dental implants; MICROSTRUCTURE; MORPHOLOGY; TEMPERATURE;
D O I
10.3390/molecules28166054
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Nano Zirconia (ZrO2) has been used in dental implants due to having excellent mechanical properties and biocompatibility that match the requirements for the purpose. Zirconia undergoes phase transformation during heating: monoclinic (room temperature to 1170 degrees C), tetragonal (1170 degrees C to 2370 degrees C), and cubic (>2370 degrees C). Most useful mechanical properties can be obtained when zirconia is in a multiphase form or in partially stabilized zirconia (PSZ), which is achieved by adding small amounts of a metal oxide dopant, such as MgO (magnesia). This study aimed to synthesize nano Mg-PSZ from a local resource found in West Kalimantan, Indonesia, and examine its structural stability, biochemical stability, and mechanical properties. Nano Mg-PSZ was prepared from a zircon local to Indonesia, from West Kalimantan Province, MgSO4.7H(2)O, and polyethylene glycol (PEG)-6000 was used as a template. The obtained t-ZrO2 after calcination at 800 degrees C was shown to be stable at room temperature. The highest percentage of the t-ZrO2 phase was obtained at Zr0.95Mg0.05O2 with a variation of 99.5%. The hardness of Mg-PSZ increased from 554 MPa for ZrO2 without MgO doping to 5266 MPa for ZrO2 with a doping of 10% MgO. An in vitro biodegradation test showed that the greater the concentration of MgO in doping the ZrO2, the greater the degradation resistance of Mg-PSZ in simulated body fluid (SBF) solution.
引用
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页数:12
相关论文
共 49 条
[21]   Effects of sintering temperatures on micro-morphology, mechanical properties, and bioactivity of bone scaffolds containing calcium silicate [J].
Kaewsichan, Lupong ;
Riyapan, Daungporn ;
Prommajan, Phanida ;
Kaewsrichan, Jasadee .
SCIENCEASIA, 2011, 37 (03) :240-246
[22]   MECHANICAL-PROPERTIES OF THE BINARY TITANIUM-ZIRCONIUM ALLOYS AND THEIR POTENTIAL FOR BIOMEDICAL MATERIALS [J].
KOBAYASHI, E ;
MATSUMOTO, S ;
DOI, H ;
YONEYAMA, T ;
HAMANAKA, H .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH, 1995, 29 (08) :943-950
[23]  
Kodal M., 2019, CARBON BASED NANOFIL, P325, DOI DOI 10.1016/B978-0-12-817342-8.00011-1
[24]   How useful is SBF in predicting in vivo bone bioactivity? [J].
Kokubo, T ;
Takadama, H .
BIOMATERIALS, 2006, 27 (15) :2907-2915
[25]  
Kokubo T, 2008, WOODHEAD PUBL MATER, P1
[26]   Mechanism of Reduced Sintering Temperature of Al2O3-ZrO2 Nanocomposites Obtained by Microwave Hydrothermal Synthesis [J].
Koltsov, Iwona ;
Smalc-Koziorowska, Julita ;
Przesniak-Welenc, Marta ;
Malysa, Maria ;
Kimmel, Giora ;
McGlynn, Jessica ;
Ganin, Alexey ;
Stelmakh, Swietlana .
MATERIALS, 2018, 11 (05)
[27]  
La Kilo A, 2019, J KIM SAINS APLIKASI, V22, P129, DOI [10.14710/jksa.22.4.129-135, 10.14710/jksa.22.4.129-135, DOI 10.14710/JKSA.22.4.129-135]
[28]   Effect of different compositions on characteristics and osteoblastic activity of microporous biphasic calcium phosphate bioceramics [J].
Lee, Youn-Il ;
Kim, Young-Jin .
MATERIALS TECHNOLOGY, 2017, 32 (08) :496-504
[29]   Effects of adding nano metal powders on thermooxidative degradation of poly(ethylene glycol) [J].
Lin, Z. ;
Han, X. ;
Wang, T. ;
Li, S. .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2008, 91 (03) :709-714
[30]   Controlling the formation of Na2ZrSiO5 in alkali fusion process for zirconium oxychloride production [J].
Liu, Jingchong ;
Song, Jing ;
Qi, Tao ;
Zhang, Changqiao ;
Qu, Jingkui .
ADVANCED POWDER TECHNOLOGY, 2016, 27 (01) :1-8