Copper-Catalyzed Allylic C(sp3)-H Sulfonylation of Cyclic Olefins

被引：2

作者：

Liu Chunyang ^{[1
]}

Li Yan ^{[1
]}

Zhang Qian ^{[1
,2
]}

机构：

[1] Northeast Normal Univ, Dept Chem, Changchun 130024, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 43卷 / 03期

基金：

中国国家自然科学基金;

关键词：

copper-catalyzed; radicals; allylic C(sp(3))-H; sulfonation reaction; allylic sulfone; C-H; COUPLING REACTION; ALLYLATION; FUNCTIONALIZATION; AMINATION; SULFONES; ALLENES; ALKYNES; AMINES; AMINOCYANATION;

D O I：

10.6023/cjoc202211028

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly efficient copper-catalyzed direct sulfonylation of allylic C(sp3)-H bond was developed using simple cyclic olefins and sodium sulfite as starting materials. A series of allylic sulfone derivatives were synthesized in moderate to good yields under mild conditions. The mechanism study shows that the reaction might involve radical intermediates.

引用

页码：1091 / 1101

页数：11

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