Covalent organic frameworks for photocatalysis: Synthesis, structural features, fundamentals and performance

Covalent organic frameworks (COFs) are a new class of crystalline porous materials obtained from cova-lently attached organic building units. By virtue of the unique characteristics such as periodic and well-defined structures, low-density, high surface area, excellent stability as well as desired semiconductor -like behavior, COFs have gained tremendous attention for functional applications in many fields, espe-cially in photocatalysis. In this review, we summarize the different methods for the synthesis of COFs, such as solvothermal synthesis, microwave synthesis, ionothermal synthesis, room temperature solution synthesis, mechanochemical synthesis and interfacial synthesis firstly. Then, the structural features of COFs including diversity, tailorability, stability and porosity are provided. Afterwards, the fundamentals and advantages of COFs for photocatalysis are briefly introduced. Following this, the photocatalytic appli-cations of COF-based materials toward H2 production, CO2 reduction, organic transformation and pollu-tion degradation are discussed. Meanwhile, a series of strategies are highlighted to improve photocatalytic performance for the understanding of the structure-property relationship in this part. Finally, the remaining challenges and prospects on further development of efficient COF-based photocat-alysts are indicated.(c) 2022 Elsevier B.V. All rights reserved.