Development and Digital Light Processing 3D Printing of a Vitrimer Composed of Glycerol 1,3-Diglycerolate Diacrylate and Tetrahydrofurfuryl Methacrylate

被引：6
作者：
Grauzeliene, Sigita [1 ]
Schuller, Anne-Sophie [2 ]
Delaite, Christelle [2 ]
Ostrauskaite, Jolita [1 ]
机构：
[1] Kaunas Univ Technol, Dept Polymer Chem & Technol, LT-50254 Kaunas, Lithuania
[2] Univ Strasbourg, Univ Haute Alsace, Lab Photochim & Ingn Macromol EA4567, F-68093 Mulhouse, France
来源：
ACS APPLIED POLYMER MATERIALS | 2023年 / 5卷 / 09期
关键词：
vitrimer; glycerol; biobased; shapememory; weldability; repairability; DLP3D printing; MECHANICAL-PROPERTIES; NETWORKS;
D O I：
10.1021/acsapm.3c01018
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The development of biobased reshapable and repairablevitrimershas received extensive attention due to the growing focus on an environmentallyfriendly society. Therefore, the objective of this research was tosynthesize sustainable polymers with an environmentally friendly strategycombining the benefits of renewable resources, UV curing, and vitrimers.Two biobased monomers, glycerol 1,3-diglycerolate diacrylate and tetrahydrofurfurylmethacrylate, were chosen for the preparation of UV-curable resinsand tested by real-time photorheometry and RT-FTIR spectroscopy todetermine their suitability for digital light processing (DLP) 3Dprinting. DLP 3D-printed polymer showed shape memory, weldability,and repairability capabilities by triggering the dynamic transesterificationprocess at high temperatures. The vitrimer with a weight ratio of60:40 of glycerol 1,3-diglycerolate diacrylate and tetrahydrofurfurylmethacrylate showed shape memory properties with a recovery ratioof 100% and a 7-fold improved tensile strength compared to the originalsample, confirming efficient weldability and repairability.
引用
收藏
页码：6958 / 6965
页数：8
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Fu, Renli ;
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[32]   Preparation of Si3N4 ceramic based on digital light processing 3D printing and precursor infiltration and pyrolysis [J].
Wang, Xuye ;
Li, Yalin ;
Liu, Bingshan ;
Li, Shan ;
Duan, Wenyan ;
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Chen, Fei .
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, 2023, 20 (02) :1017-1027
[33]   Preparation of high performance dense Al2O3 ceramics by digital light processing 3D printing technology [J].
Wei, Sijie ;
Han, Guifang ;
Zhang, Xu ;
Sun, Jian ;
Zhang, Jingde ;
Wang, Weili ;
Zhang, Weibin ;
Yang, Lianhong ;
Li, Jianzhang .
CERAMICS INTERNATIONAL, 2024, 50 (01) :2083-2095
[34]   Development and evaluation of Al2O3-ZrO2 composite processed by digital light 3D printing [J].
Zheng, Tianqi ;
Wang, Wei ;
Sun, Jinxing ;
Liu, Jing ;
Bai, Jiaming .
CERAMICS INTERNATIONAL, 2020, 46 (07) :8682-8688
[35]   Digital Light Processing-Based 3D Printing of Cell-Seeding Hydrogel Scaffolds with Regionally Varied Stiffness [J].
Xue, Dai ;
Zhang, Jiaxin ;
Wang, Yancheng ;
Mei, Deqing .
ACS BIOMATERIALS SCIENCE & ENGINEERING, 2019, 5 (09) :4825-4833
[36]   Preparation of excellent performance ZTA ceramics and complex shaped components using digital light processing 3D printing technology [J].
Wei, Sijie ;
Han, Guifang ;
Zhang, Xu ;
Sun, Jian ;
Wang, Weili ;
Zhang, Jiatai ;
Zhang, Zhixuan ;
Zhang, Weibin ;
Jingde, Zhang ;
Yang, Lianhong ;
Li, Jianzhang ;
Qiao, Ying .
JOURNAL OF ALLOYS AND COMPOUNDS, 2024, 980
[37]   Digital light processing 3D printing of surface-oxidized Si3N4 coated by silane coupling agent [J].
Yang, Ping ;
Sun, Zhenfei ;
Huang, Shengwu ;
Ou, Jun ;
Wu, Shanghua ;
Jiang, Qiangguo ;
Li, Dichen .
JOURNAL OF ASIAN CERAMIC SOCIETIES, 2022, 10 (01) :69-82
[38]   Investigation of mechanical and electrical properties of photopolymer nanocomposites reinforced with carbon-based nanoparticles produced by digital light processing 3D printing technique [J].
Eren, Ogulcan ;
Yuksel, Nurullah ;
Sahin, Ismail .
POLYMER COMPOSITES, 2024,
[39]   Digital Light Processing 3D Printing of Isosorbide- and Vanillin-Based Ester and Ester-Imine Thermosets: Structure-Property Recyclability Relationships [J].
Liguori, Anna ;
Oliva, Eugenia ;
Sangermano, Marco ;
Hakkarainen, Minna .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2023, 11 (39) :14601-14613
[40]   Functionalized poly L-lactic acid synthesis and optimization of process parameters for 3D printing of porous scaffolds via digital light processing (DLP) method [J].
Saed, Arvin Bagheri ;
Behravesh, Amir Hossein ;
Hasannia, Sadegh ;
Alavinasab Ardebili, Seyyed Alireza ;
Akhoundi, Behnam ;
Pourghayoumi, Majid .
JOURNAL OF MANUFACTURING PROCESSES, 2020, 56 :550-561
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