Elevated corrosion resistance and improved magnetic properties of sintered Nd-Fe-B magnets via the infiltration of DyCr film

The low coercivity at high temperature and poor corrosion resistance limit the application field of Nd-Fe-B magnets. In this work, a DyCr film was prepared on the surface of Nd-Fe-B magnet through magnetron sputtering, and then subjected to grain boundary diffusion (GBD) to improve magnetic properties and enhance corrosion resistance. The results show that the residual Cr-rich film exists on the surface of NdFeB magnets, acting as a protective coating to enhance the corrosion resistance, which is evidenced by the weight loss experiment and scanning electron microscopy (SEM) image. Moreover, Cr element in the grain boundary phase increase the electrochemical potential from - 0.985 to - 0.733 V, which is also beneficial in improving corrosion resistance. Transmission electron microscope (TEM) analysis confirmed that the crystal structure of intergranular phase remained unchanged after diffusion, i.e. BCC-RE2O3 (RE=Rare Earth) phase. The coercivity was improved significantly, obtaining an increment of 19.4% comparing to that of initial magnet, which is attributed to the formed Dy-rich shell with high magnetocrystalline anisotropy field and the improved distribution of grain boundary phase. This suggests that it is feasible to fabricate high coer-civity magnets and strong corrosion resistance only through grain boundary diffusion, which is expected to further shorten the processing flow of Nd-Fe-B magnets.(c) 2023 Elsevier B.V. All rights reserved.