Crystal structure and fluorescence-based sensor properties of a Metal-Organic Framework

被引:1
作者
Chang, Jing-Lin [1 ]
Wu, Jun-Feng [1 ]
Zhang, Jia-Wei [1 ]
Cui, Kai [1 ]
Liu, Zhi-Qiang [1 ]
机构
[1] Anqing Normal Univ, Sch Chem & Chem Engn, Anhui Prov Key Lab Funct Opt Elect & Magnet Mat, Anqing 246011, Anhui, Peoples R China
来源
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2024年 / 79卷 / 2-3期
关键词
Metal-Organic Frameworks; fluorescence; cadmium; acetone; Fe3+ ions; ADSORPTION PROPERTIES; LIGANDS; FE(III); IONS;
D O I
10.1515/znb-2023-0077
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A Metal-Organic Framework (MOF) based on a tricarboxylic acid ligand (H3L = biphenyl-2,4 ',5-tricarboxylic acid), namely [Cd-3(L)(2)(H2O)(4)] (1), had been prepared and characterized by elemental analysis, IR spectroscopy, powder X-ray diffraction (PXRD), thermogravimetric analyses (TGA), and single-crystal X-ray diffraction. Fluorescence studies showed that 1 has high quenching efficiency for testing acetone and Fe3+ ions in aqueous systems. Therefore, it can be used as a new type of fluorescence probe to detect solvent molecules and metal ions in water.
引用
收藏
页码:81 / 87
页数:7
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