Distribution characteristics and optical properties of carbonaceous aerosol: brown carbon and black carbon in Nanchang, inland China

PM2.5 samples were collected from October 31, 2019, to November 10, 2019, in Nanchang for 10 consecutive days. The mass concentrations of PM2.5 and carbon components were measured, and the distribution charac-teristics of carbonaceous aerosols were discussed. The optical properties of carbonaceous aerosols were quan-tified by the thermal-optical method and solvent extraction method, respectively. The results showed that the average concentrations of organic carbon (OC) and elemental carbon (EC) in aerosols in Nanchang were 11.79 +/- 3.86 and 3.51 +/- 1.59 mu gm- 3, respectively. The average OC/EC was 3.62, and OC2, OC3, OC4 and EC1 accounted for relatively large proportions (19.55, 24.96, 22.37 and 17.38%). Carbonaceous aerosols in Nanchang were greatly affected by coal combustion, vehicle exhaust emissions and secondary organic carbon (SOC) formation. For particulate brown carbon (BrC), the average light absorption coefficient (babs) and mass absorption efficiency (MAE) at 405 nm were 16.87 Mm-1 and 1.49 m2g- 1, respectively. The average Absorption angstrom ngstro center dot m exponent (AAE) was 8.58. For water-soluble organic carbon (WSOC) and methanol-soluble organic carbon (MSOC), the average babs,365,WSOC and babs,365,MSOC were 14.79 and 22.51 Mm-1, respectively. The mean values of AAE300-600, WSOC and AAE300-600,MSOC were 4.17 and 4.84, respectively. The mean MAE365,WSOC and MAE365,MSOC were 1.83 and 2.18 m2g- 1, respectively. The mean value of MAEBC at 405 nm was 10.28 m2g- 1. The optical properties of particulate BrC and dissolved BrC were similar at 405 nm. The light absorption of BrC cannot be ignored, although BC was the main light absorption component.