Denitrative Mizoroki-Heck reaction of unactivated alkenes

被引：6

作者：

Zhang, Fei ^{[1
]}

Wang, Fei ^{[1
]}

Zhao, Yao ^{[1
]}

Chen, Rizhi ^{[2
]}

Wu, Xiaojin ^{[1
]}

机构：

[1] Nanjing Tech Univ, Inst Adv Synth, Sch Chem & Mol Engn, Nanjing 211816, Peoples R China

[2] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Nanjing 211816, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2023年 / 10卷 / 09期

基金：

中国国家自然科学基金;

关键词：

ARYLBORONIC ACIDS; COUPLING REACTION; NITROARENES; AMINATION; CHLORIDES; CATALYST; SUZUKI;

D O I：

10.1039/d3qo00132f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general palladium-catalyzed denitrative Mizoroki-Heck reaction of unactivated alkenes was developed. Most topical classes of nitroarenes efficiently react with various unactivated alkenes with high E/Z selectivity. A gram-scale reaction, chemoselective dual Heck transformation and modification of complex molecules have further demonstrated that the denitrative reaction of unactivated alkenes is a powerful complementary strategy to the classical Mizoroki-Heck reaction.

引用

页码：2193 / 2197

页数：5

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