Four-functional iron/copper sulfide heterostructure for alkaline hybrid zinc batteries and water splitting

被引：35
作者：
Dang, Jiaxin [1 ]
Yin, Mingming [1 ]
Pan, Dianhui [2 ]
Tian, Ziqi [2 ]
Chen, Genman [1 ]
Zou, Jiaqun [1 ]
Miao, He [1 ]
Wang, Qin [3 ]
Yuan, Jinliang [1 ]
机构：
[1] Ningbo Univ, Fac Maritime & Transportat, Ningbo 315211, Peoples R China
[2] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315211, Peoples R China
[3] Ningbo Univ, Fac Sci, Dept Microelect Sci & Engn, Ningbo 315211, Peoples R China
来源：
CHEMICAL ENGINEERING JOURNAL | 2023年 / 457卷
基金：
中国国家自然科学基金;
关键词：
Alkaline hybrid zinc batteries; Iron; copper sulfides; Water splitting; Oxygen catalysis; Ion conversion reactions; HIGH-ENERGY DENSITY; CATHODE MATERIALS; OXYGEN EVOLUTION; ION BATTERIES; ACTIVE-SITES; ELECTROCATALYST; NANOSHEETS; COPPER; REDUCTION; ELECTRODE;
D O I：
10.1016/j.cej.2023.141357
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Developing the tri-functional catalysts to facilitate the oxygen evolution, oxygen reduction and hydrogen evo-lution reactions (OER, ORR and HER) is meaningful for zinc-air batteries (ZABs) and water splitting. Herein, we construct a novel metal sulfide heterostructure (INF-FeCuS) composed of Cu7S4 and Fe0.95S1.05. INF-FeCuS ex-hibits the superior tri-functional catalytic property with the OER, ORR and HER potentials of 1.45 V at 100 mA cm-2, 0.68 V at 10 mA cm-2, 292 mV at 100 mA cm-2 respectively. INF-FeCuS with a high ion conversion ability also can be used in the alkaline zinc battery with a discharge specific capacity of 446.0 mAh/g. Using the four -functional INF-FeCuS, we can fabricate a new-type of alkaline hybrid zinc battery (AHZB) with a peak power density of 203.4 mW cm-2 and energy efficiency of over 70 %. Interestingly, a single AHZB with INF-FeCuS can drive the electrolyzer with INF-FeCuS to produce hydrogen.
引用
收藏
页数：10
相关论文
共 60 条
[51]   Integration of partially phosphatized bimetal centers into trifunctional catalyst for high-performance hydrogen production and flexible Zn-air battery [J].
Yang, Miaosen ;
Liu, Yifan ;
Sun, Jiaqiang ;
Zhang, Shusheng ;
Liu, Xijun ;
Luo, Jun .
SCIENCE CHINA-MATERIALS, 2022, 65 (05) :1176-1186
[52]   Oxygen Vacancies Dominated NiS2/CoS2 Interface Porous Nanowires for Portable Zn-Air Batteries Driven Water Splitting Devices [J].
Yin, Jie ;
Li, Yuxuan ;
Lv, Fan ;
Lu, Min ;
Sun, Ke ;
Wang, Wei ;
Wang, Lei ;
Cheng, Fangyi ;
Li, Yefei ;
Xi, Pinxian ;
Guo, Shaojun .
ADVANCED MATERIALS, 2017, 29 (47)
[53]   High-performance alkaline hybrid zinc batteries with heterostructure nickel/cobalt sulfide [J].
Yin, Mingming ;
Miao, He ;
Dang, Jiaxin ;
Chen, Bin ;
Zou, Jiaqun ;
Chen, Genman ;
Li, Hong .
JOURNAL OF POWER SOURCES, 2022, 545
[54]   Bimetallic Nickel Cobalt Sulfide as Efficient Electrocatalyst for Zn-Air Battery and Water Splitting [J].
Zhang, Jingyan ;
Bai, Xiaowan ;
Wang, Tongtong ;
Xiao, Wen ;
Xi, Pinxian ;
Wang, Jinlan ;
Gao, Daqiang ;
Wang, John .
NANO-MICRO LETTERS, 2019, 11 (01)
[55]   Enhanced light harvesting and electron-hole separation for efficient photocatalytic hydrogen evolution over Cu7S4-enwrapped Cu2O nanocubes [J].
Zhang, Mengmeng ;
Chen, Zelin ;
Wang, Yang ;
Zhang, Jinfeng ;
Zheng, Xuerong ;
Rao, Dewei ;
Han, Xiaopeng ;
Zhong, Cheng ;
Hu, Wenbin ;
Deng, Yida .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2019, 246 :202-210
[56]   N, P doped carbon nanotubes confined WN-Ni Mott-Schottky heterogeneous electrocatalyst for water splitting and rechargeable zinc-air batteries [J].
Zhang, Quan ;
Luo, Fang ;
Long, Xue ;
Yu, Xinxin ;
Qu, Konggang ;
Yang, Zehui .
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY, 2021, 298
[57]   Efficient Co-doped pyrrhotite Fe0.95S1.05 nanoplates for electrochemical water splitting [J].
Zheng, Dehua ;
Jing, Zhongxin ;
Zhao, Qingyun ;
Kim, Yena ;
Li, Ping ;
Xu, Huizhong ;
Li, Zaifeng ;
Lin, Jianjian .
CHEMICAL ENGINEERING JOURNAL, 2020, 402
[58]   Tuning Co2+ Coordination in Cobalt Layered Double Hydroxide Nanosheets via Fe3+ Doping for Efficient Oxygen Evolution [J].
Zheng, Yue ;
Gao, Rui ;
Qiu, Yunsheng ;
Zheng, Lirong ;
Hu, Zhongbo ;
Liu, Xiangfeng .
INORGANIC CHEMISTRY, 2021, 60 (07) :5252-5263
[59]   A Function-Separated Design of Electrode for Realizing High-Performance Hybrid Zinc Battery [J].
Zhong, Yijun ;
Xu, Xiaomin ;
Liu, Pengyun ;
Ran, Ran ;
Jiang, San Ping ;
Wu, Hongwei ;
Shao, Zongping .
ADVANCED ENERGY MATERIALS, 2020, Wiley-VCH Verlag (10)
[60]   Fe-Ni-Mo Nitride Porous Nanotubes for Full Water Splitting and Zn-Air Batteries [J].
Zhu, Chunling ;
Yin, Zhuoxun ;
Lai, Weihong ;
Sun, Yue ;
Liu, Lina ;
Zhang, Xitian ;
Chen, Yujin ;
Chou, Shu-Lei .
ADVANCED ENERGY MATERIALS, 2018, 8 (36)
123456