Synthesis and performance of a cathode catalyst derived from areca nut husk in microbial fuel cell

被引:17
|
作者
Subran, Nikitha [1 ]
Ajit, Karnapa [1 ]
Krishnan, Haribabu [1 ]
Pachiyappan, Senthilkumar [2 ]
Ramaswamy, Palani [3 ]
机构
[1] Natl Inst Technol, Dept Chem Engn, Kozhikode 673601, India
[2] Saveetha Engn Coll, Dept Chem Engn, Chennai 602105, India
[3] Sri Venkateshwara Coll Engn, Dept Chem Engn, Sriperumbudur 602117, Tamil Nadu, India
关键词
Microbial fuel cell; Areca nut husk; Cathode catalyst; Electrical conductivity; Bioelectricity; Sustainable energy; DOPED POROUS CARBON; METAL-FREE ELECTROCATALYSTS; OXYGEN REDUCTION REACTION; AIR-CATHODE; WASTE-WATER; NITROGEN; GENERATION; SLUDGE; LEAVES; ONION;
D O I
10.1016/j.chemosphere.2022.137303
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The role of the cathode catalyst is crucial in a single chamber Microbial Fuel Cell (MFC) to overcome the energy barrier. The present work aims todevelop a metal-free cathode catalyst from anagro-waste, areca nut husk and to evaluate its performance in MFC. Activated carbon with amorphous graphitic structure was synthesised at a pyrolysis temperature of 500 degrees C from the areca nut husk. The surface area of activated carbon is 1261.6 m2/g with an average particle size of 35.23 mu m. The electrochemical characterisation of the cathode in oxygen saturated atmosphere reveals, a loading rate of 5 mg/cm2 possesses an equivalent conductivity to that of Pt catalyst. An Open Circuit voltage of 864 mV with a power density of 590 mW/m2 and a current density of 1.03517 A/m2 at 611.8 omega was obtained. These results make the novel metal free catalyst a potential alternative to metal-based catalysts.
引用
收藏
页数:7
相关论文
共 50 条
  • [31] Comparing the performance of microbial fuel cell with mechanical aeration and photosynthetic aeration in the cathode chamber
    Don, Chamath D. Y. Yahampath Arachchige
    Babel, Sandhya
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (31) : 16751 - 16761
  • [32] Cathode catalyst prepared from bacterial cellulose for ethanol fermentation stillage treatment in microbial fuel cell
    Li, Huiyu
    Gao, Ming
    Wang, Pan
    Ma, Hongzhi
    Liu, Ting
    Ni, Jin
    Wang, Qunhui
    Chang, Tien-Chin
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2021, 40 : 256 - 261
  • [33] Activated carbon nanofibers as an alternative cathode catalyst to platinum in a two-chamber microbial fuel cell
    Ghasemi, Mostafa
    Shahgaldi, Samaneh
    Ismail, Manal
    Kim, Byung Hong
    Yaakob, Zahira
    Daud, Wan Ramli Wan
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (21) : 13746 - 13752
  • [34] Carbon nanotube/polypyrrole nanocomposite as a novel cathode catalyst and proper alternative for Pt in microbial fuel cell
    Ghasemi, Mostafa
    Daud, Wan Ramli Wan
    Hassan, Sedky H. A.
    Jafary, Taheyeh
    Rahimnejad, Mostafa
    Ahmad, Azyi
    Yazdi, Mohammad H.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (08) : 4872 - 4878
  • [35] Carbon supported nickel-phthalocyanine/MnOx as novel cathode catalyst for microbial fuel cell application
    Tiwari, B. R.
    Noori, Md. T.
    Ghangrekar, M. M.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (36) : 23085 - 23094
  • [36] Performance of tungsten oxide/polypyrrole composite as cathode catalyst in single chamber microbial fuel cell
    Karthick, S.
    Sumisha, A.
    Haribabu, K.
    JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2020, 8 (06):
  • [37] Biomass derived activated carbon cathode performance for sustainable power generation from Microbial Fuel Cells
    Bose, Debajyoti
    Sridharan, Shanmathi
    Dhawan, Himanshi
    Vijay, Parthasarthy
    Gopinath, Margavelu
    FUEL, 2019, 236 : 325 - 337
  • [38] CuSe decorated carbon nanotubes as a high performance cathode catalyst for microbial fuel cells
    Tan, Liang
    Liu, Zhao-Qing
    Li, Nan
    Zhang, Jia-Yi
    Zhang, Lei
    Chen, Shuang
    ELECTROCHIMICA ACTA, 2016, 213 : 283 - 290
  • [39] Design of NiCo2S4@ZnAl-LDH/TiO2@MXene synthesis as promising cathode catalyst for enhancing electrochemical performance in microbial fuel cell
    Chen, Junfeng
    Zhang, Yiwen
    Wang, Jingyu
    Wang, Mingkun
    Liu, Jinyu
    Wu, Yiqun
    Zhao, Yongyue
    Wang, Renjun
    Yang, Yuewei
    Liu, Yanyan
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 55 : 625 - 634
  • [40] Xerogel based catalyst for improved cathode performance in microbial fuel cells
    Sen Thapa, Bhim
    Seetharaman, S.
    Chetty, Raghuram
    Chandra, T. S.
    ENZYME AND MICROBIAL TECHNOLOGY, 2019, 124 : 1 - 8