Synthesis and performance of a cathode catalyst derived from areca nut husk in microbial fuel cell

被引:17
|
作者
Subran, Nikitha [1 ]
Ajit, Karnapa [1 ]
Krishnan, Haribabu [1 ]
Pachiyappan, Senthilkumar [2 ]
Ramaswamy, Palani [3 ]
机构
[1] Natl Inst Technol, Dept Chem Engn, Kozhikode 673601, India
[2] Saveetha Engn Coll, Dept Chem Engn, Chennai 602105, India
[3] Sri Venkateshwara Coll Engn, Dept Chem Engn, Sriperumbudur 602117, Tamil Nadu, India
关键词
Microbial fuel cell; Areca nut husk; Cathode catalyst; Electrical conductivity; Bioelectricity; Sustainable energy; DOPED POROUS CARBON; METAL-FREE ELECTROCATALYSTS; OXYGEN REDUCTION REACTION; AIR-CATHODE; WASTE-WATER; NITROGEN; GENERATION; SLUDGE; LEAVES; ONION;
D O I
10.1016/j.chemosphere.2022.137303
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The role of the cathode catalyst is crucial in a single chamber Microbial Fuel Cell (MFC) to overcome the energy barrier. The present work aims todevelop a metal-free cathode catalyst from anagro-waste, areca nut husk and to evaluate its performance in MFC. Activated carbon with amorphous graphitic structure was synthesised at a pyrolysis temperature of 500 degrees C from the areca nut husk. The surface area of activated carbon is 1261.6 m2/g with an average particle size of 35.23 mu m. The electrochemical characterisation of the cathode in oxygen saturated atmosphere reveals, a loading rate of 5 mg/cm2 possesses an equivalent conductivity to that of Pt catalyst. An Open Circuit voltage of 864 mV with a power density of 590 mW/m2 and a current density of 1.03517 A/m2 at 611.8 omega was obtained. These results make the novel metal free catalyst a potential alternative to metal-based catalysts.
引用
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页数:7
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