Homogeneous catalysis with nitrous oxide

被引：9

作者：

Severin, Kay ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne EPFL, Inst Sci & Ingenierie Chim, CH-1015 Lausanne, Switzerland

来源：

TRENDS IN CHEMISTRY | 2023年 / 5卷 / 08期

关键词：

CHEMISTRY;

D O I：

10.1016/j.trechm.2022.12.008

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nitrous oxide (N2O; 'laughing gas') is a powerful oxidant, but chemical transformations are hampered by the inert character of this gas. Recent advances in using N2O as an oxidant in metal-catalyzed reactions are discussed. The focus will be on reactions that occur under mild conditions in homogeneous solutions.

引用

页码：574 / 576

页数：3

共 15 条

[1] Deoxygenation of Nitrous Oxide and Nitro Compounds Using Bis(N-Heterocyclic Silylene)Amido Iron Complexes as Catalysts [J].

Chen, Xi ;

Wang, Hao ;

Du, Shaozhi ;

Driess, Matthias ;

Mo, Zhenbo .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (07)

[2] Homogeneous molecular catalysis of the electrochemical reduction of N2O to N2: redox vs. chemical catalysis [J].

Deeba, Rana ;

Chardon-Noblat, Sylvie ;

Costentin, Cyrille .

CHEMICAL SCIENCE, 2021, 12 (38) :12726-12732

[3] Nitrous Oxide as a Hydrogen Acceptor for the Dehydrogenative Coupling of Alcohols [J].

Gianetti, Thomas L. ;

Annen, Samuel P. ;

Santiso-Quinones, Gustavo ;

Reiher, Markus ;

Driess, Matthias ;

Gruetzmacher, Hansjoerg .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (05) :1854-1858

[4] Reduction of Nitrogen Oxides by Hydrogen with Rhodium(I)-Platinum(II) Olefin Complexes as Catalysts [J].

Jurt, Pascal ;

Abels, Anne Sofie ;

Gamboa-Carballo, Juan Jose ;

Fernandez, Israel ;

Le Corre, Gregoire ;

Aebli, Marcel ;

Baker, Matthew G. ;

Eiler, Frederik ;

Mueller, Fabian ;

Worle, Michael ;

Verel, Rene ;

Gauthier, Sebastien ;

Trincado, Monica ;

Gianetti, Thomas L. ;

Grutzmacher, Hansjorg .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (48) :25372-25380

[5] Oxidative Coupling Reactions of Grignard Reagents with Nitrous Oxide [J].

Kiefer, Gregor ;

Jeanbourquin, Loic ;

Severin, Kay .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (24) :6302-6305

[6] Catalytic oxygenation of organic substrates: Toward greener ways for incorporating oxygen [J].

Landaeta, Vanessa R. ;

Rodriguez-Lugo, Rafael E. .

INORGANICA CHIMICA ACTA, 2015, 431 :21-47

[7] Catalytic synthesis of phenols with nitrous oxide [J].

Le Vaillant, Franck ;

Calbet, Ana Mateos ;

Gonzalez-Pelayo, Silvia ;

Reijerse, Edward J. ;

Ni, Shengyang ;

Busch, Julia ;

Cornella, Josep .

NATURE, 2022, 604 (7907) :677-+

[8] Ni-Catalyzed Oxygen Transfer from N2O onto sp3 -Hybridized Carbons [J].

Ni, Shengyang ;

Le Vaillant, Franck ;

Mateos-Calbet, Ana ;

Martin, Ruben ;

Cornella, Josep .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (40) :18223-18228

[9] Catalytic Activation of N2O at a Low-Valent Bismuth Redox Platform [J].

Pang, Yue ;

Leutzsch, Markus ;

Nothling, Nils ;

Cornella, Josep .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (46) :19473-19479

[10] Nitrous oxide in oxidation chemistry and catalysis: application and production [J].

Parmon, VN ;

Panov, GI ;

Uriarte, A ;

Noskov, AS .

CATALYSIS TODAY, 2005, 100 (1-2) :115-131

← 1 2 →