共 62 条
Structural, Electrical and Magnetic Properties of Low Dimensional Pr-Doped Co-Zn Ferrite Nanoparticles
被引:9
作者:
Badiger, Hanamanta
[1
]
Matteppanavar, Shidaling
[2
]
Hegde, B. G.
[1
]
机构:
[1] Rani Channamma Univ, Dept Phys, Belagavi 591156, India
[2] KLE Soc Basavaprabhu Kore Arts Sci & Commerce Coll, Dept Phys, Chikodi 591201, India
关键词:
Auto combustion method;
Cole-Cole plot;
Debye type of relaxation;
Spinel ferrite;
Maxwell-Wagner;
DEPENDENT DIELECTRIC-PROPERTIES;
COFE2O4;
NANOPARTICLES;
COMBUSTION SYNTHESIS;
ZINC FERRITE;
THIN-FILMS;
COBALT;
CONDUCTIVITY;
TEMPERATURE;
RELAXATION;
FREQUENCY;
D O I:
10.1007/s10948-023-06503-w
中图分类号:
O59 [应用物理学];
学科分类号:
摘要:
In recent years multiferroic materials have gained importance due to their multifunctional properties and their tremendous applications in technological field. We undertook the study of transition metal ion doped AB(2)O(4) low dimensional multiferroic materials. Here we synthesized the Pr doped CoZnFe2O4 (CZFO) with general formula Co0.5Zn0.5-xPrxFe2O4 (x = 0.00, 0.01,0.02,0.03,0.04,0.05) (CZPFO) by modified auto combustion method with Citric acid as a fuel and detailed room temperature Structural, Electrical and Magnetic properties were investigated. Room temperature XRD patterns shows cubic structure Fd-3 m space group, without any impurities. Rietveld refinement carried out to extract the lattice parameters, cell volume and bond distance. VESTA programming used to obtain polyhedral structure for all the samples. The average crystalline size of the CZPFO sample is around 5-10 nm. The room temperature M-H loop implies the ferromagnetic nature with reduction of magnetic saturation. For morphological analysis the field emission scanning electron microscope (FE-SEM) notice the large, densely and contiguously populated microstructure along with some agglomeration type of particle texture. EDAX confirms the chemical stoichiometry composition. Room temperature frequency dependence of the dielectric properties showed a major effect of the grain and grain boundary. The dielectric constant and dielectric loss of all the samples decreased sharply with increasing frequency. This is referred to as the Maxwell-Wagner type of polarization in accordance with Koop's theory. The Cole-Cole plot from impedance spectra reveals Debye type of relaxation. Modulus analysis reveals the presence of conduction phenomenon with decreasing the both real and imaginary parts of relative permeability with respect to frequency.
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页码:675 / 684
页数:10
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