Synthesis of Thioamides via Decarboxylative/Oxidative Cross-Coupling Reaction by Visible-Light Photocatalysis

被引：2
|
作者：
Sarkar, Subhankar [1 ,2 ]
Pal, Satyajit [1 ]
Santra, Sougata
Zyryanov, Grigory V. [2 ,3 ]
Ghosh, Susanta [4 ]
Majee, Adinath [1 ]
机构：
[1] Visva Bharati Cent Univ, Dept Chem, Santini Ketan 731235, India
[2] Ural Fed Univ, Chem Engn Inst, Dept Organ & Biomol Chem, 19 Mira St, Ekaterinburg 620002, Russia
[3] Russian Acad Sci, I Ya Postovskiy Inst Organ Synth, Ural Div, 22 S Kovalevskoy St, Ekaterinburg 620219, Russia
[4] Visva Bharati Cent Univ, Integrated Sci Educ & Res Ctr, Santini Ketan 731235, India
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 12卷 / 06期
基金：
俄罗斯科学基金会;
关键词：
Arylglyoxylic acids; Radical cross-coupling; Tetraalkylthiuram disulfides; Thioamides; Visible light; ALPHA-OXOCARBOXYLIC ACIDS; METAL-FREE; SUBSTITUTION; ACYLATION; ALDEHYDES; REAGENT;
D O I：
10.1002/ajoc.202300141
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient and new approach has been developed for decarboxylative/oxidative cross-coupling reaction between arylglyoxylic acids and N,N,N ',N '-tetraalkylthiuram disulfides to afford aryl thioamide using a catalytic amount of Eosin Y as a photocatalyst. This reaction protocol offers a metal, base and sulfurating reagent-free synthesis of a variety of aryl thioamides with moderate to excellent yields.
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页数：6
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