Composite lithium conducting solid electrolytes based on zwitterionic plastic crystals and polymer nanoparticles

Organic ionic plastic crystals (OIPCs) are promising materials for the development of solid-state electrolytes for next-generation energy storage devices with improved safety. Zwitterionic plastic crystals, in which the cationic and anionic groups are covalently bound, are a promising alternative to traditional OIPC-based electrolytes as they offer a route to higher target ion transport by reducing the number of competing ions. Incorporating polymeric nanoparticles (NPs) into OIPC matrixes can create solid-state electrolytes with increased mechanical stability and enhanced ionic conductivity, but this has never been investigated for the plastic zwitterion-based electrolytes. In this work, we designed self-standing, conductive zwitterionic-based composite materials by combining lithium functionalised polymer nanoparticles with a zwitterion. The further addition of either lithium salt or solvent can be used to optimise conductivity and/or transference number of the solid electrolyte. The novel composite electrolytes prepared via this strategy offer a promising new pathway for the development of conductive and safe electrolytes for all solid-state lithium metal batteries. Zwitterion-based composites, formed using lithium sulfonamide-functionalized polymer nanoparticles, are promising materials for the development of solid-state electrolytes for next-generation energy storage devices, with improved safety.